Metallomicelle catalyzed aerobic tandem desilylation/Glaser reaction in water

被引：34
|
作者：
Tang, Shanyu [1 ]
Li, Longjia [1 ]
Ren, Xuanhe [1 ]
Li, Jiao [1 ]
Yang, Guanyu [1 ]
Li, Heng [1 ]
Yuan, Bingxin [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
来源：
GREEN CHEMISTRY | 2019年 / 21卷 / 11期
基金：
中国国家自然科学基金;
关键词：
ORGANIC-SYNTHESIS; POLYYNES; SYSTEMS; THIOLS; DESILYLATION/DIMERIZATION; POLYMERIZATION; SPECTROSCOPY; SONOGASHIRA; ACTIVATOR; SOLVENTS;
D O I：
10.1039/c8gc03815e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
PEG-grafted nitrogen ligands were synthesized. The corresponding copper complexes serve as metallomicellar nanoreactors for the aerobic tandem desilylation/ Glaser coupling of TMS-protected alkynes in water. The protocol is also suitable for base-free homocoupling of terminal alkynes. The metallomicellar catalyst could be recycled 5 times with minor loss of reactivity.
引用
收藏
页码：2899 / 2904
页数：6
相关论文
共 50 条
  • [1] Tandem silylation—desilylation reaction in the synthesis of N-methyl carboxamides
    N. F. Lazareva
    I. M. Lazarev
    Russian Chemical Bulletin, 2022, 71 : 735 - 739
  • [2] Cobalt-Catalyzed Glaser-type Homocoupling Reaction
    Han, Jun-Fa
    Guo, Peng
    Chen, Lin
    Ye, Ke-Yin
    SYNTHESIS-STUTTGART, 2022, 54 (08): : 1989 - 1995
  • [3] Benzotriazole as an Efficient Ligand in Cu-Catalyzed Glaser Reaction
    Singh, Mala
    Singh, Anoop S.
    Mishra, Nidhi
    Agrahari, Anand K.
    Tiwari, Vinod K.
    ACS OMEGA, 2019, 4 (01): : 2418 - 2424
  • [4] Tandem silylation-desilylation reaction in the synthesis of N-methyl carboxamides
    Lazareva, N. F.
    Lazarev, I. M.
    RUSSIAN CHEMICAL BULLETIN, 2022, 71 (04) : 735 - 739
  • [5] Catalytic Fehling's Reaction: An Efficient Aerobic Oxidation of Aldehyde Catalyzed by Copper in Water
    Liu, Mingxin
    Li, Chao-Jun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (36) : 10806 - 10810
  • [6] Pd/C-catalyzed ligand-free and aerobic Suzuki reaction in water
    Rao, Xiaofeng
    Liu, Chun
    Zhang, Yixia
    Gao, Zhanming
    Jin, Zilin
    CHINESE JOURNAL OF CATALYSIS, 2014, 35 (03) : 357 - 361
  • [7] Nickel chloride promoted glaser coupling reaction in hot water
    Li, PH
    Wang, L
    Wang, M
    Yan, JC
    CHINESE CHEMICAL LETTERS, 2004, 15 (11) : 1295 - 1298
  • [8] Nickel Chloride Promoted Glaser Coupling Reaction in Hot Water
    Pin Hua LI
    ChineseChemicalLetters, 2004, (11) : 1295 - 1298
  • [9] Aerobic oxidation reaction catalyzed by graphene oxide
    Park, Jung Hyun
    Raza, Faizan
    Yim, Dabin
    Kim, Jong-Ho
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [10] MECHANISM OF AEROBIC OXIDASE REACTION CATALYZED BY PEROXIDASE
    YAMAZAKI, I
    PIETTE, LH
    BIOCHIMICA ET BIOPHYSICA ACTA, 1963, 77 (01) : 47 - &
12345