CoSe2 Clusters as Efficient Co-Catalyst Modified CdS Nanorod for Enhance Visible Light Photocatalytic H2 Evolution

被引:17
作者
Gan, Ruizhou [1 ,2 ,3 ]
Ma, Xiaohua [1 ,2 ,3 ]
Wang, Guorong [1 ,2 ,3 ]
Jin, Zhiliang [1 ,2 ,3 ]
机构
[1] North Minzu Univ, Sch Chem & Chem Engn, Yinchuan 750021, Peoples R China
[2] North Minzu Univ, Ningxia Key Lab Solar Chem Convers Technol, Yinchuan 750021, Peoples R China
[3] North Minzu Univ, Key Lab Chem Engn & Technol, State Ethn Affairs Commiss, Yinchuan 750021, Peoples R China
来源
CATALYSTS | 2019年 / 9卷 / 07期
关键词
CoSe2; clusters; CdS nanorod; hydrogen evolution; photocatalysis; H-2-PRODUCTION ACTIVITY; HYDROGEN; TIO2; GRAPHENE; FABRICATION; WATER; CO; NANOCOMPOSITE; NANOPARTICLES; MECHANISMS;
D O I
10.3390/catal9070616
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CoSe2, as a kind of co-catalyst, would replace noble metals element to dope pure CdS. The CoSe2/CdS photocatalyst could be synthesized by simple physical mixing. With the introduction of CoSe2, especially 30% CoSe2/CdS, hydrogen production would be about 500 mu mol within 5 h, five times that of pure CdS under the same conditions. The CoSe2/CdS photocatalyst could bear four cycles of hydrogen evolution and sustain the hydrogen production, with a minor decrease. In other words, the electron transition velocity would surge along with the introduction of CoSe2 particles. The CoSe2 could be deemed as the predator and exit of electrons to inspire the detachment of the hole-electron pairs and relieve the recombination of the hole-electron pairs.
引用
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页数:15
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