CoSe2 Clusters as Efficient Co-Catalyst Modified CdS Nanorod for Enhance Visible Light Photocatalytic H2 Evolution

被引:17
作者
Gan, Ruizhou [1 ,2 ,3 ]
Ma, Xiaohua [1 ,2 ,3 ]
Wang, Guorong [1 ,2 ,3 ]
Jin, Zhiliang [1 ,2 ,3 ]
机构
[1] North Minzu Univ, Sch Chem & Chem Engn, Yinchuan 750021, Peoples R China
[2] North Minzu Univ, Ningxia Key Lab Solar Chem Convers Technol, Yinchuan 750021, Peoples R China
[3] North Minzu Univ, Key Lab Chem Engn & Technol, State Ethn Affairs Commiss, Yinchuan 750021, Peoples R China
来源
CATALYSTS | 2019年 / 9卷 / 07期
关键词
CoSe2; clusters; CdS nanorod; hydrogen evolution; photocatalysis; H-2-PRODUCTION ACTIVITY; HYDROGEN; TIO2; GRAPHENE; FABRICATION; WATER; CO; NANOCOMPOSITE; NANOPARTICLES; MECHANISMS;
D O I
10.3390/catal9070616
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CoSe2, as a kind of co-catalyst, would replace noble metals element to dope pure CdS. The CoSe2/CdS photocatalyst could be synthesized by simple physical mixing. With the introduction of CoSe2, especially 30% CoSe2/CdS, hydrogen production would be about 500 mu mol within 5 h, five times that of pure CdS under the same conditions. The CoSe2/CdS photocatalyst could bear four cycles of hydrogen evolution and sustain the hydrogen production, with a minor decrease. In other words, the electron transition velocity would surge along with the introduction of CoSe2 particles. The CoSe2 could be deemed as the predator and exit of electrons to inspire the detachment of the hole-electron pairs and relieve the recombination of the hole-electron pairs.
引用
收藏
页数:15
相关论文
共 43 条
[1]   In-situ fabrication of CuS/g-C3N4 nanocomposites with enhanced photocatalytic H2-production activity via photoinduced interfacial charge transfer [J].
Chen, Tianjun ;
Song, Chengjie ;
Fan, Mingshan ;
Hong, Yuanzhi ;
Hu, Bo ;
Yu, Longbao ;
Shi, Weidong .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (17) :12210-12219
[2]  
Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/NCHEM.1589, 10.1038/nchem.1589]
[3]   A survey of photocatalytic materials for environmental remediation [J].
Di Paola, Agatino ;
Garcia-Lopez, Elisa ;
Marci, Giuseppe ;
Palmisano, Leonardo .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 211 :3-29
[4]   Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst [J].
Fu, Junwei ;
Xu, Quanlong ;
Low, Jingxiang ;
Jiang, Chuanjia ;
Yu, Jiaguo .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 243 :556-565
[5]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[6]   Photocatalytic Reduction of CO2 on TiO2 and Other Semiconductors [J].
Habisreutinger, Severin N. ;
Schmidt-Mende, Lukas ;
Stolarczyk, Jacek K. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (29) :7372-7408
[7]   Peculiar synergetic effect of MoS2 quantum dots and graphene on Metal-Organic Frameworks for photocatalytic hydrogen evolution [J].
Hao, Xuqiang ;
Jin, Zhiliang ;
Yang, Hao ;
Lu, Gongxuan ;
Bi, Yingpu .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 210 :45-56
[8]   Behavior of borate complex anion on the stabilities and the hydrogen evolutions of ZnxCo3-xO4 decorated graphene [J].
Hao, Xuqiang ;
Jin, Zhiliang ;
Wang, Fang ;
Xu, Jing ;
Min, Shixiong ;
Yuan, Hong ;
Lu, Gongxuan .
SUPERLATTICES AND MICROSTRUCTURES, 2015, 82 :599-611
[9]   Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting [J].
Hisatomi, Takashi ;
Kubota, Jun ;
Domen, Kazunari .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7520-7535
[10]   Efficient photocatalytic reduction of CO2 by amine-functionalized g-C3N4 [J].
Huang, Qian ;
Yu, Jiaguo ;
Cao, Shaowen ;
Cui, Can ;
Cheng, Bei .
APPLIED SURFACE SCIENCE, 2015, 358 :350-355