Monomeric silver(I) β-diketiminate complexes

被引：33
作者：
Chiong, Hendrich A. [1 ]
Daugulis, Olafs [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77004 USA
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 17期
关键词：
D O I：
10.1021/om0603621
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New silver(I) beta-diketiminate complexes have been prepared and characterized. Monomeric complexes with ethylene (4), triphenylphosphine (5), and IMes (IMes = 1,3-dimesitylimidazol-2-ylidene) (8) as well as a dinuclear acetonitrile complex (3) were characterized by H-1 NMR, C-13 NMR, elemental analysis, and X-ray crystallography. These complexes are stable in the solid state at ambient temperature and inert atmosphere.
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页码：4054 / 4057
页数：4
相关论文
共 41 条
[1]   HOMOLEPTIC CARBENE SILVER(I) AND CARBENE COPPER(I) COMPLEXES [J].
ARDUENGO, AJ ;
DIAS, HVR ;
CALABRESE, JC ;
DAVIDSON, F .
ORGANOMETALLICS, 1993, 12 (09) :3405-3409
[2]   The chemistry of β-diketiminatometal complexes [J].
Bourget-Merle, L ;
Lappert, MF ;
Severn, JR .
CHEMICAL REVIEWS, 2002, 102 (09) :3031-3065
[3]   A new class of (μ-η2:η2-disulfido)dicopper complexes:: Synthesis characterization and disulfido exchange [J].
Brown, EC ;
Aboelella, NW ;
Reynolds, AM ;
Aullón, G ;
Alvarez, S ;
Tolman, WB .
INORGANIC CHEMISTRY, 2004, 43 (11) :3335-3337
[4]  
Burgos M, 2003, EUR J INORG CHEM, P2170
[5]  
CHO BY, 2005, ORG LETT, V7, P4383
[6]   Chemical redox agents for organometallic chemistry [J].
Connelly, NG ;
Geiger, WE .
CHEMICAL REVIEWS, 1996, 96 (02) :877-910
[7]   A silver-catalyzed intramolecular amidation of saturated C-H bonds [J].
Cui, Y ;
He, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (32) :4210-4212
[8]   Efficient aziridination of olefins catalyzed by a unique disilver(I) compound [J].
Cui, Y ;
He, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (52) :16202-16203
[9]   Discrete bridging and terminal copper carbenes in copper-catalyzed cyclopropanation [J].
Dai, XL ;
Warren, TH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (32) :10085-10094
[10]   Dioxygen activation by a neutral β-diketiminato copper(I) ethylene complex [J].
Dai, XL ;
Warren, TH .
CHEMICAL COMMUNICATIONS, 2001, (19) :1998-1999
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