A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear Co3II/III clusters

被引：28

作者：

Stamatatos, Theocharis C. ^{[1
,2
]}

Katsoulakou, Eugenia ^{[2
]}

Terzis, Aris ^{[3
]}

Raptopoulou, Catherine P. ^{[3
]}

Winpenny, Richard E. P. ^{[1
]}

Perlepes, Spyros P. ^{[2
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Univ Patras, Dept Chem, Patras 26504, Greece

[3] NCSR Demokritos, Inst Mat Sci, Aghia Paraskevi 15310, Greece

来源：

POLYHEDRON | 2009年 / 28卷 / 9-10期

基金：

英国工程与自然科学研究理事会;

关键词：

Cobalt(III) complexes; Complexes as ligands strategy; Crystal structures; Mixed-valence cobalt(II/III) complexes; 2-Pyridyloxime ligands; Trinuclear cobalt clusters; SINGLE-MOLECULE MAGNET; COBALT(III/II/III) COMPLEXES; COORDINATION CHEMISTRY; BRIDGING SULFITO; COBALT COMPLEX; LIGANDS; COBALT(II/III); MAGNETIZATION; RELAXATION; PYRIDINE;

D O I：

10.1016/j.poly.2008.10.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of the 2-pyridyl oxime ligands (LH) 2-pyridinealdoxime, methyl 2-pyridyl ketone oxime and phenyl 2-pyridyl ketone oxime in Co chemistry has been investigated and led to two families of compounds. The first family includes the mononuclear octahedral, low-spin complexes [Co-II(L)(3)], while the second family consists of the trinuclear, mixed-valent linear clusters [(Co2CoII)-Co-III(L)(6)]X-2 (X = ClO4-, PF6-). The latter are prepared by the reactions of the former with an appropriate Con source. The structural, physical and spectroscopic properties of the complexes are described. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1638 / 1645

页数：8

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