Helix-sense-selective Degradation of Poly[4-dodecyloxy-3,5-bis(hydroxymethyl)phenylacetylene] by Selective Photocyclic Aromatization (SCAT) Using Circularly Polarized Light (CPL)

被引：16

作者：

Miyata, Mari ^{[1
]}

Teraguchi, Masahiro ^{[1
,2
]}

Endo, Hiromichi ^{[1
]}

Kaneko, Takashi ^{[1
,2
]}

Aoki, Toshiki ^{[1
,2
]}

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Niigata Univ, Ctr Educ & Res Environm Technol, Inst Sci & Technol, Niigata 9502181, Japan

来源：

CHEMISTRY LETTERS | 2014年 / 43卷 / 09期

基金：

日本学术振兴会;

关键词：

INTRAMOLECULAR HYDROGEN-BONDS; CHAIN HELICITY; CONJUGATED POLYMER; POLY(PHENYLACETYLENE)S; MEMBRANES;

D O I：

10.1246/cl.140469

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Helix-sense-selective photodegaradation of poly[4-dodecyloxy-3,5-bis(hydroxymethyl)phenylacetylene] (poly(DoDHPA)) in membrane state was achieved by selective photocyclic aromatization (SCAT) using single-handed circularly polarized light (CPL). This is the first example of kinetic optical resolution of helical polymers by using CPL.

引用

页码：1476 / 1477

页数：2

共 21 条

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