Helix-sense-selective Degradation of Poly[4-dodecyloxy-3,5-bis(hydroxymethyl)phenylacetylene] by Selective Photocyclic Aromatization (SCAT) Using Circularly Polarized Light (CPL)

被引：16
作者：
Miyata, Mari [1 ]
Teraguchi, Masahiro [1 ,2 ]
Endo, Hiromichi [1 ]
Kaneko, Takashi [1 ,2 ]
Aoki, Toshiki [1 ,2 ]
机构：
[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan
[2] Niigata Univ, Ctr Educ & Res Environm Technol, Inst Sci & Technol, Niigata 9502181, Japan
来源：
CHEMISTRY LETTERS | 2014年 / 43卷 / 09期
基金：
日本学术振兴会;
关键词：
INTRAMOLECULAR HYDROGEN-BONDS; CHAIN HELICITY; CONJUGATED POLYMER; POLY(PHENYLACETYLENE)S; MEMBRANES;
D O I：
10.1246/cl.140469
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Helix-sense-selective photodegaradation of poly[4-dodecyloxy-3,5-bis(hydroxymethyl)phenylacetylene] (poly(DoDHPA)) in membrane state was achieved by selective photocyclic aromatization (SCAT) using single-handed circularly polarized light (CPL). This is the first example of kinetic optical resolution of helical polymers by using CPL.
引用
收藏
页码：1476 / 1477
页数：2
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