Sound Velocity of Liquid Fe-P at High Pressure

被引:6
作者
Kinoshita, Daisuke [1 ]
Nakajima, Yoichi [1 ,2 ]
Kuwayama, Yasuhiro [2 ,3 ]
Hirose, Kei [3 ,4 ]
Iwamoto, Asaki [1 ]
Ishikawa, Daisuke [2 ,5 ]
Baron, Alfred Q. R. [2 ]
机构
[1] Kumamoto Univ, Dept Phys, Kumamoto 8608555, Japan
[2] RIKEN SPring 8 Ctr, Mat Dynam Lab, Mikazuki, Hyogo 6795148, Japan
[3] Univ Tokyo, Dept Earth & Planetary Sci, Tokyo 1130033, Japan
[4] Tokyo Inst Technol, Earth Life Sci Inst, Tokyo 1528550, Japan
[5] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2020年 / 257卷 / 11期
基金
日本科学技术振兴机构; 日本学术振兴会;
关键词
Earth' s core; high pressure; inelastic X-ray scattering; liquid Fe alloys; phosphorus content; sound velocity; OUTER CORE CONDITIONS; DENSITY-MEASUREMENTS; IRON; EARTHS; ALLOYS; BEHAVIOR; STATE;
D O I
10.1002/pssb.202000171
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The longitudinal sound wave (P-wave) velocity of liquid Fe75P25 alloy is determined up to 60 GPa using inelastic X-ray scattering with laser-heated diamond anvil cell. Phosphorus is found to have negligible effect on the P-wave velocity of liquid Fe under high-pressure conditions. Based on the P-wave and pressure data, an adiabatic Murnaghan equation of state for liquid Fe75P25 is constructed, yielding to the adiabatic bulk modulus K-S0 = 94.9 +/- 7.1 GPa and its pressure derivative K'(S) = 3.56 +/- 0.18, respectively, at 1 bar with the density of 5.94 g cm(-3) at 2000 K. The addition of phosphorus decreases the bulk modulus and density of liquid Fe under high-pressure conditions, which minimizes the effect on the velocity. Using the equation of state, the P-wave velocity and density of liquid Fe75P25 are estimated under Earth's liquid outer core conditions. Comparison with seismological observations suggests an upper limit of phosphorus in liquid core of 14.6 +/- 3.9 wt%.
引用
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页数:7
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