9,10-Dihydro-9,10-diboraanthracene: Supramolecular Structure and Use as a Building Block for Luminescent Conjugated Polymers

被引：163

作者：

Lorbach, Andreas ^{[1
]}

Bolte, Michael ^{[1
]}

Li, Haiyan ^{[2
]}

Lerner, Hans-Wolfram ^{[1
]}

Holthausen, Max C. ^{[1
]}

Jaekle, Frieder ^{[2
]}

Wagner, Matthias ^{[1
]}

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany

[2] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 25期

关键词：

boron; fluorescence; hydroboration; organoboranes; polymers; 3-COORDINATE ORGANOBORON COMPOUNDS; AMORPHOUS MOLECULAR MATERIALS; BRIDGED POLY(FERROCENYLENE)S; HYDROBORATION POLYMERIZATION; ELECTROLUMINESCENT DEVICES; BORON ATOM; BINDING; SYSTEMS; FAMILY; ACID;

D O I：

10.1002/anie.200901226

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Building bridges: The title compound forms an unprecedented polymeric structure with bridging B-H-B three-center two-electron bonds in the solid state. This organoborane serves as an efficient precursor for the preparation of boron-doped π-conjugated polymers by hydroboration polymerization with a functionalized 1,4-diethynylbenzene (see picture). These polymers form thin films that show intense green luminescence. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4584 / 4588

页数：5

共 38 条

[1]

[Anonymous], ANGEW CHEM

[2] SYNTHESIS OF THE MONOMERIC HB2,4,6-I-PR3C6H2 AND THE X-RAY CRYSTAL-STRUCTURES OF [HB2,4,6-ME3C6H22]2 AND HBTRIP2 [J].

BARTLETT, RA ;

DIAS, HVR ;

OLMSTEAD, MM ;

POWER, PP ;

WEESE, KJ .

ORGANOMETALLICS, 1990, 9 (01) :146-150

[3] Bitopic bis- and tris(1-pyrazolyl)borate ligands: Syntheses and structural characterization [J].

Bieller, S ;

Zhang, F ;

Bolte, M ;

Bats, JW ;

Lerner, HW ;

Wagner, M .

ORGANOMETALLICS, 2004, 23 (09) :2107-2113

[4] HYDROBORATION - KINETICS AND MECHANISM [J].

BROWN, HC ;

CHANDRASEKHARAN, J ;

WANG, KK .

PURE AND APPLIED CHEMISTRY, 1983, 55 (09) :1387-1414

[5] Syntheses and structures of 6,13-dihydro-6,13-diborapentacenes:: π-stacking in heterocyclic analogues of pentacene [J].

Chen, Jinhui ;

Kampf, Jeff W. ;

Ashe, Arthur J., III .

ORGANOMETALLICS, 2008, 27 (15) :3639-3641

[6] A new design strategy for organic optoelectronic materials by lateral boryl substitution [J].

Elbing, Mark ;

Bazan, Guillermo C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (05) :834-838

[7] Applications of three-coordinate organoboron compounds and polymers in optoelectronics [J].

Entwistle, CD ;

Marder, TB .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4574-4585

[8]

Entwistle CD, 2002, ANGEW CHEM INT EDIT, V41, P2927, DOI 10.1002/1521-3773(20020816)41:16<2927::AID-ANIE2927>3.0.CO

[9]

2-L

[10]

Gunther H., 1983, NMR-Spektroskopie

← 1 2 3 4 →