Complex coacervate core micelles

被引:351
|
作者
Voets, Ilja K. [1 ]
de Keizer, Arie [1 ]
Stuart, Martien A. Cohen [1 ]
机构
[1] Univ Wageningen & Res Ctr, Lab Phys Chem & Colloid Sci, NL-6703 HB Wageningen, Netherlands
关键词
DOUBLE-HYDROPHILIC BLOCK; OPPOSITELY CHARGED SURFACTANT; WATER-SOLUBLE COMPLEXES; CATIONIC RANDOM COPOLYMER; MIXED POLYMERIC MICELLES; SODIUM DODECYL-SULFATE; COMB-TYPE COPOLYMERS; GENE-TRANSFER AGENTS; POLY-L-LYSINE; POLY(ETHYLENE OXIDE)-BLOCK-POLY(SODIUM METHACRYLATE);
D O I
10.1016/j.cis.2008.09.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this review we present an overview of the literature on the co-assembly of neutral-ionic block, graft, and random copolymers with oppositely charged species in aqueous solution. Oppositely charged species include synthetic (co)polymers of various architectures, biopolymers - such as proteins, enzymes and DNA multivalent ions, metallic nanoparticles, low molecular weight surfactants, polyelectrolyte block copolymer micelles. metallo-supra molecular polymers, equilibrium polymers, etcetera. The resultant structures are termed complex coacervate core/polyion complex/block ionomer complex/interpolyelectrolyte complex micelles (or vesicles); i.e., in short C3Ms (or C3Vs) and PIC, BIC or IPEC micelles (and vesicles). Formation, structure, dynamics, properties, and function will be discussed. We focus on experimental work: theory and modelling will not be discussed. Recent developments in applications and micelles with heterogeneous coronas are emphasized. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:300 / 318
页数:19
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