Original hybrid membrane-catalytic reactor for the Co-Production of syngas and ultrapure hydrogen in the processes of dry and steam reforming of methane, ethanol and DME

被引：29

作者：

Fedotov, A. S. ^{[1
]}

Antonov, D. O. ^{[1
]}

Uvarov, V., I ^{[2
]}

Tsodikov, M., V ^{[1
]}

机构：

[1] RAS, AV Topchiev Inst Petrochem Synth, Leninsky Prospect 29, Moscow 119991, Russia

[2] RAS, Merzhanov Inst Struct Macrokinet & Mat Sci, Ul Academician Osipyan 8, Moscow 142432, Chernogolovka, Russia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2018年 / 43卷 / 14期

基金：

俄罗斯科学基金会;

关键词：

Hybrid membrane-catalytic reactor; Porous ceramic converter; Self-propagating high-temperature synthesis (SHS); Dry and steam reforming of methane; Ethanol and dimethyl ether; Syngas and hydrogen production; FUEL; CHALLENGES; CO;

D O I：

10.1016/j.ijhydene.2018.02.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An original hybrid membrane-catalytic reactor (HMCR) was developed for the coproduction of syngas and ultrapure hydrogen from fossil and renewable organic sources (methane and ethanol), as well as from synthetic feedstock (dimethyl ether) via dry and steam reforming. HMCR is a facility in which a porous ceramic catalytic converter prepared by self-propagating high-temperature synthesis (SHS) is integrated with a hydrogen-selective palladium-containing membrane. Due to separation of hydrogen from the reaction site and according to Le Chatelier-Brown principle it enables reforming to proceed effectively under milder temperature conditions as compared to a conventional reactor with a stationary bulk catalyst bed. On the basis of HMCR there can be developed mobile and small-size ultrapure hydrogen production units for fine processes of organic synthesis and electricity generation. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：7046 / 7054

页数：9

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