Large third-order optical nonlinearity of ZnO-Bi2O3-B2O3 glass-ceramic containing Bi2ZnB2O7 nanocrystals

被引：28

作者：

Zeng, Huidan ^{[1
]}

Liu, Zhao ^{[1
]}

Jiang, Qi ^{[1
,2
]}

Li, Bo ^{[3
]}

Yang, Chao ^{[3
]}

Shang, Zhengjun ^{[3
]}

Ren, Jing ^{[1
]}

Chen, Guorong ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China

[2] S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China

[3] E China Normal Univ, Minist Educ, Key Lab Polar Mat & Devices, Shanghai 200241, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2014年 / 34卷 / 16期

基金：

上海市自然科学基金;

关键词：

Glass-ceramic; Nonlinear crystal; Third-order optical nonlinearity; B2O3-BI2O3; GLASSES; NLO CRYSTALS; GROWTH; SUSCEPTIBILITIES; FIBERS;

D O I：

10.1016/j.jeurceramsoc.2014.06.031

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Homogeneous transparent optical glass-ceramics precipitated with unique nonlinear crystals are promising materials for photonic applications. We have utilized heat treatment method to prepare transparent ZnO-Bi2O3-B2O3 glass-ceramic containing Bi2ZnB2O7 nonlinear nanocrystals. A large third-order nonlinear susceptibility chi((3)) of glass-ceramic is measured by Z-scan technique, which mainly attributed to unique [BiO6] and [B2O5] units in Bi2ZnB2O7 crystal structure and the quantum size effect of nanoparticles. The discovery is of great potential in the application of nonlinear optical integrated devices. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：4383 / 4388

页数：6

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