Oxidation of aliphatic and benzylic alcohols by Oxone®, catalysed by 12-tungstocobaltate (II)

被引：24

作者：

Maradur, SP

Halligudi, SB

Gokavi, GS ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India

[2] Natl Chem Lab, Catalysis Div, Pune, Maharashtra, India

来源：

CATALYSIS LETTERS | 2004年 / 96卷 / 3-4期

关键词：

homogeneous catalysis; oxidation; alcohols; polyoxometalates (POM); Oxone (R);

D O I：

10.1023/B:CATL.0000030115.24111.5c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Keggin-type polyoxometalate (POM) 12-tungstocobaltate (II) ([Co-II(W12O40)](6-)) has been used as a catalyst for the oxidation of aliphatic and benzylic alcohols to the corresponding carbonyl compounds. The reduced ( POM) formed in the oxidation of alcohols is re-oxidized by potassium peroxomonopersulphate.

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收藏

页码：165 / 167

页数：3

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