Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation

被引：221

作者：

Deria, Pravas ^{[1
]}

Bury, Wojciech ^{[1
,2
]}

Hupp, Joseph T. ^{[1
]}

Farha, Omar K. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 16期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; ENERGY MIGRATION; STABILITY; CATALYSIS; EXCHANGE; EXAMPLE;

D O I：

10.1039/c3cc48562e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvent-assisted ligand incorporation (SALI) was utilized to efficiently insert various carboxylate-derived functionalities into the Zr-based metal-organic framework NU-1000 as charge compensatingmoieties strongly bound to the Zr-6 nodes. SALI-derived functionalities are accessible for further chemical reactions such as click chemistry, imine condensation and pyridine quaternization.

引用

页码：1965 / 1968

页数：4

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