Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation

被引:211
作者
Deria, Pravas [1 ]
Bury, Wojciech [1 ,2 ]
Hupp, Joseph T. [1 ]
Farha, Omar K. [1 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland
基金
美国国家科学基金会;
关键词
METAL-ORGANIC FRAMEWORKS; ENERGY MIGRATION; STABILITY; CATALYSIS; EXCHANGE; EXAMPLE;
D O I
10.1039/c3cc48562e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solvent-assisted ligand incorporation (SALI) was utilized to efficiently insert various carboxylate-derived functionalities into the Zr-based metal-organic framework NU-1000 as charge compensatingmoieties strongly bound to the Zr-6 nodes. SALI-derived functionalities are accessible for further chemical reactions such as click chemistry, imine condensation and pyridine quaternization.
引用
收藏
页码:1965 / 1968
页数:4
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