All-Solid-State Lithium Batteries with Sulfide Electrolytes and Oxide Cathodes

被引：297

作者：

Wu, Jinghua ^{[1
,2
]}

Shen, Lin ^{[1
,2
]}

Zhang, Zhihua ^{[1
]}

Liu, Gaozhan ^{[1
,2
]}

Wang, Zhiyan ^{[1
,2
]}

Zhou, Dong ^{[1
]}

Wan, Hongli ^{[1
,2
]}

Xu, Xiaoxiong ^{[3
,4
]}

Yao, Xiayin ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China

[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China

[3] Zhejiang Funlithium New Energy Technol Co Ltd, Ningbo 315201, Zhejiang, Peoples R China

[4] Ganfeng Lithium Co Ltd, Xinyu 338015, Jiangxi, Peoples R China

来源：

ELECTROCHEMICAL ENERGY REVIEWS | 2021年 / 4卷 / 01期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

All-solid-state lithium batteries; Sulfide electrolytes; Oxide cathodes; Interfaces; ATOMIC LAYER DEPOSITION; ENHANCED ELECTROCHEMICAL PERFORMANCE; HIGH IONIC-CONDUCTIVITY; LIQUID-PHASE TECHNIQUE; SUPERIONIC CONDUCTOR; LI6PS5X X; INTERPHASE FORMATION; SECONDARY BATTERIES; CRYSTAL-STRUCTURE; LICOO2; ELECTRODE;

D O I：

10.1007/s41918-020-00081-4

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

All-solid-state lithium batteries (ASSLBs) have attracted increasing attention due to their high safety and energy density. Among all corresponding solid electrolytes, sulfide electrolytes are considered to be the most promising ion conductors due to high ionic conductivities. Despite this, many challenges remain in the application of ASSLBs, including the stability of sulfide electrolytes, complex interfacial issues between sulfide electrolytes and oxide electrodes as well as unstable anodic interfaces. Although oxide cathodes remain the most viable electrode materials due to high stability and industrialization degrees, the matching of sulfide electrolytes with oxide cathodes is challenging for commercial use in ASSLBs. Based on this, this review will present an overview of emerging ASSLBs based on sulfide electrolytes and oxide cathodes and highlight critical properties such as compatible electrolyte/electrode interfaces. And by considering the current challenges and opportunities of sulfide electrolyte-based ASSLBs, possible research directions and perspectives are discussed.

引用

页码：101 / 135

页数：35

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