Double-well structure and microscopic branching in the O(1D)+HCl reaction

被引：29

作者：

Alvariño, JM ^{[1
]}

Rodríguez, A

Laganà, A

Hernández, ML

机构：

[1] Univ Salamanca, Dept Quim Fis, E-37008 Salamanca, Spain

[2] Univ Salamanca, Dept Fis Atmosfera, E-37008 Salamanca, Spain

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 313卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(99)00857-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By performing a quasiclassical trajectory study, we have confirmed that the title reaction can take place via different paths even when leading to the same product (microscopic branching). However, contrary to a previous hypothesis, no collinear collisions were found to contribute to the reaction. Therefore, the backward-forward structure of the ClO product angular distribution obtained in the crossed-beam experiment has to be ascribed to the combination of a backward peak associated with insertion-like collisions and a forward peak associated with side attachment of O on Cl. Proper combinations of insertion and attachment contributions also rationalize other properties of the title reaction. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：299 / 306

页数：8

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