A two-dimensional copper(II) coordination polymer comprising discrete left-and right-handed helical chains

被引:39
作者
Wang, RH [1 ]
Han, L [1 ]
Sun, YQ [1 ]
Gong, YQ [1 ]
Yuan, DQ [1 ]
Hong, MC [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
关键词
coordination polymer; copper(II); helical chain; hydrogen bonds;
D O I
10.1016/j.molstruc.2004.02.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel two-dimensional copper(H) coordination polymer comprising discrete left-handed and right-handed helical chains bridged by 1,3-di(4-pyridyl)propane (dpp), [{Cu-2(dpp)(2)(H2O)(2)(dpa)(2)}(H2O)(2)(CH3OH)(2)]n (1) (H(2)dpa = diphenic acid), has been prepared and characterized by single-crystal X-ray diffraction analysis. The hydrogen bonding interactions between the adjacent layers extend 1 into a three-dimensional supramolecular architecture. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 83
页数:5
相关论文
共 37 条
[1]  
Aspinall HC, 2000, ANGEW CHEM INT EDIT, V39, P2858, DOI 10.1002/1521-3773(20000818)39:16<2858::AID-ANIE2858>3.0.CO
[2]  
2-T
[3]   Structural diversity of building-blocks in coordination framework synthesis -: combining M(NO3)2 junctions and bipyridyl ligands [J].
Barnett, SA ;
Champness, NR .
COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :145-168
[4]   ONE-DIMENSIONAL COORDINATION POLYMERS - APPLICATIONS TO MATERIAL SCIENCE [J].
CHEN, CT ;
SUSLICK, KS .
COORDINATION CHEMISTRY REVIEWS, 1993, 128 (1-2) :293-322
[5]   Synthesis and resolution of (R*,R*)-(±)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane:: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates [J].
Cook, VC ;
Willis, AC ;
Zank, J ;
Wild, SB .
INORGANIC CHEMISTRY, 2002, 41 (07) :1897-1906
[6]   Interlocked chiral nanotubes assembled from quintuple helices [J].
Cui, Y ;
Lee, SJ ;
Lin, WB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6014-6015
[7]   A homochiral triple helix constructed from an axially chiral bipyridine [J].
Cui, Y ;
Ngo, HL ;
Lin, WB .
CHEMICAL COMMUNICATIONS, 2003, (12) :1388-1389
[8]   Two-dimensional homochiral manganese(II)-azido frameworks incorporating an achiral ligand: Partial spontaneous resolution and weak ferromagnetism [J].
Gao, EQ ;
Bai, SQ ;
Wang, ZM ;
Yan, CH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (17) :4984-4985
[9]  
GUO D, INORG CHEM, V41, P5978
[10]   Directed one-pot syntheses of enantiopure dinuclear silver(I) and copper(I) metallo-supramolecular double helicates [J].
Hamblin, J ;
Childs, LJ ;
Alcock, NW ;
Hannon, MJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (02) :164-169