Recent advances in transition metal migration involving reactions

被引:59
作者
Dong, Xu [1 ]
Wang, Hui [2 ]
Liu, Hui [1 ]
Wang, Fagang [1 ]
机构
[1] Shandong Univ Technol, Sch Chem & Chem Engn, 266 West Xincun Rd, Zibo 255049, Peoples R China
[2] Shandong Jincheng Kerui Chem Co Ltd, Zibo 255100, Peoples R China
基金
中国国家自然科学基金;
关键词
C-H BOND; CATALYZED ARYLATIVE CYCLIZATION; ARYLZINC REAGENTS; REGIOSELECTIVE SYNTHESIS; HECK REACTION; PALLADIUM; ACTIVATION; DERIVATIVES; COMPLEX; CYCLOCARBOPALLADATION;
D O I
10.1039/d0qo00558d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Numerous elegant methodologies involving transition-metal migration processes have received increasing attention and they have gradually developed into significant synthetic tools in the past few decades. These strategies provide novel ways to build a carbon-metal bond at a new position, where it may not be facile or straightforward to introduce a metal atom. Hence, metal-migration reactions exhibit attractive practicability in synthetic organic chemistry. This review gives an up-to-date overview of catalytic methodologies involving metal-migration processes, which are sorted into categories such as 1,2- to 1,5- and 1,7-Pd migration, 1,3- to 1,5-Rh migration, 1,4- and 1,5-Fe migration, and so on. For most of these transformations, plausible mechanisms are demonstrated elaborately. Clarification of these processes is a key point for understanding metal-migration involving reactions and developing new high-performance methodologies.
引用
收藏
页码:3530 / 3556
页数:27
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