Solvothermal synthesis and crystal structure of Zn(en)3B5O7(OH)3

被引：0
|
作者：
He Yi [1 ]
Chen Wei [1 ]
Yang Jin [1 ]
Xi Chun-Yu [1 ]
Chen Jie-Sheng [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2006年 / 22卷 / 03期
基金：
中国国家自然科学基金;
关键词：
solvothermal synthesis; crystal structure; chiral metal-complex; borate compound;
D O I：
10.1016/S1005-9040(06)60096-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new polyborate containing chiral metal-complex Zn(en)(3)B5O7 (OH)(3), where en = ethylenediamine, was synthesizedunder solvothermal conditions and structurally characterized by means of X-ray diffraction analysis. Crystal data: Zn(en)(3)B5O7 (OH)(3), monoclinic, space group P2(1)/c, a = 0. 8532(72) nm, b = 2.3340(5) nm, c = 0. 9526(92) nm, beta = 107.04(3)degrees, Z=4, V=1.8140(6) nm(3), D-c =1.694 g/cm(3), mu = 1.416 mm(-1), F(000) = 960, GOF = 1.020, R =0.0276, R-w =0.0828. There is a chiral Zn(en)(3)(2+) complex cation and an isolated B5O7 center dot (OH)(3)(2-) group in a Zn(en)(3)B5O7(OH)(3) molecule. The enantiomer of the chiral complex cation is separated orderly as Delta and Lambda configurations in the compound and the borate group consists of two B3O3 cycles linked through a bridging boron atom.
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收藏
页码：271 / 273
页数：3
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