Solvothermal synthesis and crystal structure of Zn(en)3B5O7(OH)3

被引：0

作者：

He Yi ^{[1
]}

Chen Wei ^{[1
]}

Yang Jin ^{[1
]}

Xi Chun-Yu ^{[1
]}

Chen Jie-Sheng ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2006年 / 22卷 / 03期

基金：

中国国家自然科学基金;

关键词：

solvothermal synthesis; crystal structure; chiral metal-complex; borate compound;

D O I：

10.1016/S1005-9040(06)60096-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polyborate containing chiral metal-complex Zn(en)(3)B5O7 (OH)(3), where en = ethylenediamine, was synthesizedunder solvothermal conditions and structurally characterized by means of X-ray diffraction analysis. Crystal data: Zn(en)(3)B5O7 (OH)(3), monoclinic, space group P2(1)/c, a = 0. 8532(72) nm, b = 2.3340(5) nm, c = 0. 9526(92) nm, beta = 107.04(3)degrees, Z=4, V=1.8140(6) nm(3), D-c =1.694 g/cm(3), mu = 1.416 mm(-1), F(000) = 960, GOF = 1.020, R =0.0276, R-w =0.0828. There is a chiral Zn(en)(3)(2+) complex cation and an isolated B5O7 center dot (OH)(3)(2-) group in a Zn(en)(3)B5O7(OH)(3) molecule. The enantiomer of the chiral complex cation is separated orderly as Delta and Lambda configurations in the compound and the borate group consists of two B3O3 cycles linked through a bridging boron atom.

引用

页码：271 / 273

页数：3

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