Shape selectivity in enol thioether synthesis catalyzed by zeolites

被引：1

作者：

Villemin, D ^{[1
]}

Nechab, B ^{[1
]}

机构：

[1] Univ Caen, ISMRA, Ecole Natl Super Ingenieurs Caen, UMR 6507 CNRS, F-14050 Caen, France

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 69卷 / 01期

关键词：

zeolite; clay; shape selectivity;

D O I：

10.1023/A:1005672205368

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The competitive reaction catalyzed by solid acid catalyst between two cyclohexanones (la) and (Ib) with thiophenol (2) has been studied. No selectivity was observed with the lamellar montmorillonite in contrast with microporous aluminosilicates (zeolites) where shape selectivity was observed, in particularly when the zeolites were saturated by thiophenol (2) before a competitive reaction.

引用

页码：9 / 13

页数：5

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