The prehistory of the Hammett equation

被引：0
作者：
Shorter, J [1 ]
机构：
[1] Univ Hull, Dept Chem, Hull HU6 7RX, N Humberside, England
来源：
CHEMICKE LISTY | 2000年 / 94卷 / 04期
关键词：
Hammet equation;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The evolution of linear free energy relationships is traced from the Bronsted equation for general acid-base catalysis (1924) to the Hammett rho-sigma equation for the effects of meta or para substituents on the rate or equilibrium constants of side-chain reactions of benzene derivatives (1937). In addition to a natural emphasis on Louis P. Hammett's own contributions, those of G. N. Burkhardt and his colleagues are also described, along with the extent to which these two authors interacted.
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页码：210 / 214
页数：5
相关论文
共 24 条
  • [1] [Anonymous], 1988, CORRELATION ANAL CHE
  • [2] Barron ESG, 1932, J BIOL CHEM, V97, P287
  • [3] Acid and basic catalysis
    Bronsted, JN
    [J]. CHEMICAL REVIEWS, 1928, 5 (03) : 231 - 338
  • [4] Bronsted JN, 1924, Z PHYS CHEM-STOCH VE, V108, P185
  • [5] BRONSTED JN, 1926, OM SYRE OG BASE KATA
  • [6] The hydrolysis of arylsulphuric acids. Part II. Kinetic considerations
    Burkhardt, GN
    Evans, AG
    Warhurst, E
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1936, : 25 - 26
  • [7] The hydrolysis of arylsulphuric acids - Part III
    Burkhardt, GN
    Horrex, C
    Jenkins, DI
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1936, : 1649 - 1653
  • [8] Hydrolysis of arylsulphuric acids - Part IV (a) conjugation between the benzene nucleus and unsaturated side chains (b) steric effects and the influence of alkyl groups
    Burkhardt, GN
    Horrex, C
    Jenkins, DI
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1936, : 1654 - 1660
  • [9] The hydrolysis of arylsulphuric acids. Part I.
    Burkhardt, GN
    Ford, WGK
    Singleton, E
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1936, : 17 - 25
  • [10] Influence of substituents on organic reactions a quantitative relationship
    Burkhardt, GN
    [J]. NATURE, 1935, 136 : 684 - 684
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