Activity of Cu-activated carbon fiber catalyst in wet oxidation of ammonia solution

被引:33
作者
Hung, Chang-Mao [1 ]
机构
[1] Yung Ta Inst Technol & Commerce, Dept Ind Engn & Management, Linlo 909, Pingtung, Taiwan
关键词
Catalytic wet oxidation (CWO); Ammonia; Trickle-bed reactor (TBR); Cu-ACF catalyst; COPPER-OXIDE; AIR OXIDATION; TEMPERATURE; REDUCTION; NITROGEN; CERIUM; WATER; DECOMPOSITION; REMOVAL; NH3;
D O I
10.1016/j.jhazmat.2008.12.058
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Aqueous solutions of 200-1000mg/L of ammonia were oxidized in a trickle-bed reactor using Cu-activated carbon fiber (ACF) catalysts, which were prepared by incipient wet impregnation with aqueous solutions of copper nitrate that was deposited on ACF substrates. The results reveal that the conversion of ammonia by wet oxidation in the presence of Cu-ACF catalysts was a function of the metal loading weight ratio of the catalyst. The total conversion efficiency of ammonia was 95% during wet oxidation over the catalyst at 463 K at an oxygen partial pressure of 3.0 MPa. Moreover. the effect of the initial concentration of ammonia and the reaction temperature on the removal of ammonia from the effluent streams was also studied at a liquid space velocity of less than 3.0 h(-1). (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1314 / 1320
页数:7
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