The preparation of Fe3O4/molecular-imprinted nanocomposite and the application on the recognition and separation of glyphosate

被引:9
作者
Duan, Guang Wen [1 ]
Zhang, Jin [1 ]
Li, Yang [1 ]
Xu, Yuan Ming [1 ]
Yin, Fang [1 ]
Fu, Yun Zhi [1 ,2 ]
机构
[1] Hainan Univ, Dept Mat & Chem Engn, Haikou 570228, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Colloids & Surfaces, Beijing, Peoples R China
基金
中国国家自然科学基金;
关键词
Fe3O4; glyphosate; molecularly imprinted; recognition; separation; MOLECULARLY IMPRINTED POLYMERS; LIQUID-CHROMATOGRAPHY; CHITOSAN; MICROEXTRACTION; EXTRACTION; PESTICIDES; PARTICLES; RESIDUES; SENSOR; GAS;
D O I
10.1080/15533174.2016.1186052
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The authors describe the preparation of Fe3O4-MIP (molecularly imprinted polymer) nanocomposite and the application on the recognition and separation of glyphosate. FTIR and UV confirmed the presence of imprinted sites in the nanocomposite. SEM analysis confirms the average size of Fe3O4 around 56 nm and Fe3O4-MIP around 70 nm, CV characterization showed this nanocomposite can help recognize the trace level of glyphosate. In addition, with the help of magnetic nano-Fe3O4, the recycling use of this nanocomposite is realized. Thus the authors' work provides an effective and efficient method to recognize and separate glyphosate.
引用
收藏
页码:481 / 487
页数:7
相关论文
共 27 条
[1]   Determination of organophosphorus pesticides in water samples by single drop microextraction and gas chromatography-flame photometric detector [J].
Ahmadi, F ;
Assadi, Y ;
Hosseini, SMRM ;
Rezaee, M .
JOURNAL OF CHROMATOGRAPHY A, 2006, 1101 (1-2) :307-312
[2]   Molecularly imprinted polymers for the recognition of proteins: The state of the art [J].
Bossi, A. ;
Bonini, F. ;
Turner, A. P. F. ;
Piletsky, S. A. .
BIOSENSORS & BIOELECTRONICS, 2007, 22 (06) :1131-1137
[3]   Development of a chitosan molecularly imprinted electrochemical sensor for trichlorphon determination [J].
Chen, Juanjuan ;
Lian, Huiting ;
Sun, Xiangying ;
Liu, Bin .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2012, 92 (09) :1046-1058
[4]   Synthesis and Characterization of Pt3Co@Pt Nanocomposites Using Banana Peel Extract as Novel Surfactants [J].
Duan, Guang Wen ;
Zhang, Jin ;
Xu, Yuan Ming ;
Zhang, Yu Cang ;
Fu, Yun Zhi .
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (02) :203-209
[5]   Molecularly imprinted polymers and their use in biomimetic sensors [J].
Haupt, K ;
Mosbach, K .
CHEMICAL REVIEWS, 2000, 100 (07) :2495-2504
[6]   Hydrothermal Synthesis and Magnetic Properties of Fe3O4 Octahedral Microcrystals [J].
Jiao, Hua ;
Yang, Heqing .
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (05) :732-735
[7]   Preparation and Characterization of CTAB-Coated Fe3O4 Nanoparticles [J].
Khoshnevisan, Kamyar ;
Barkhi, Mohammad ;
Zare, Davood ;
Davoodi, Daryoush ;
Tabatabaei, Meisam .
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (05) :644-648
[8]   Optimization of chitosan and β-cyclodextrin molecularly imprinted polymer synthesis for dye adsorption [J].
Kyzas, George Z. ;
Lazaridis, Nikolaos K. ;
Bikiaris, Dimitrios N. .
CARBOHYDRATE POLYMERS, 2013, 91 (01) :198-208
[9]  
Lehotay SJ, 2005, J AOAC INT, V88, P595
[10]   Preparation and properties of poly(acrylic acid) oligomer stabilized superparamagnetic ferrofluid [J].
Lin, CL ;
Lee, CF ;
Chiu, WY .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 291 (02) :411-420