Electromagnetic interference shielding by using conductive polypyrrole and metal compound coated on fabrics

被引:62
作者
Lee, CY
Lee, DE
Jeong, CK
Hong, YK
Shim, JH
Joo, J [1 ]
Kim, MS
Lee, JY
Jeong, SH
Byun, SW
Zang, DS
Yang, HG
机构
[1] Korea Univ, Dept Phys, Seoul 136701, South Korea
[2] Sungkyunkwan Univ, Dept Text Engn, Suwon 440746, South Korea
[3] Hanyang Univ, Dept Text Engn, Seoul 133791, South Korea
[4] Korea Inst Ind Technol, Cheonan 330820, South Korea
[5] Samsung SDI Co Ltd, Suwon 442391, South Korea
基金
中国国家自然科学基金;
关键词
polypyrrole; chemical polymerization; electrochemical polymerization; metal compound; fabrics; electromagnetic interference shielding efficiency;
D O I
10.1002/pat.227
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Electromagnetic interference (EMI) shielding materials of complex type of conductive polypyrrole (PPy) as an intrinsically conducting polymer and silver-palladium (AgPd) metal compound coated on woven or non-woven fabrics are synthesized. From dc conductivity and SEM photographs of PPy/fabric complexes, we discuss charge transport mechanism and the homogencity of coating on the fabrics, The EMI shielding efficiency of PPy/fabric and AgPd/fabric complexes is in the range of 8 similar to 80 dB depending on the conductivity and the additional Ag vacuum evaporation. The highest EMI shielding efficiency of PPy/fabric complexes vacuum-evaporated by Ag is similar to80 dB, indicating potential materials for military uses. We propose that PPy/fabrics are excellent RF and microwave absorber because of the relatively high absorbance and low reflectance of the materials. Copyright (C) 2002 John Wiley Sons, Ltd.
引用
收藏
页码:577 / 583
页数:7
相关论文
共 17 条
[1]   Temperature dependent conductivity behaviour of polyaniline fibres. [J].
Adams, PN ;
Pomfret, SJ ;
Monkman, AP .
SYNTHETIC METALS, 1999, 101 (1-3) :685-685
[2]  
*ASTM, 1989, D493599 ASTM
[3]   EMI SHIELDING MEASUREMENTS OF CONDUCTIVE POLYMER BLENDS [J].
COLANERI, NF ;
SHACKLETTE, LW .
IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, 1992, 41 (02) :291-297
[4]  
Epstein A. J., 1996, U.S. Patent, Patent No. 5563182
[5]   POLYANILINE SPINNING SOLUTIONS AND FIBERS [J].
HSU, CH ;
COHEN, JD ;
TIETZ, RF .
SYNTHETIC METALS, 1993, 59 (01) :37-41
[6]   High frequency electromagnetic interference shielding response of mixtures and multilayer films based on conducting polymers [J].
Joo, J ;
Lee, CY .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (01) :513-518
[7]   ELECTROMAGNETIC-RADIATION SHIELDING BY INTRINSICALLY CONDUCTING POLYMERS [J].
JOO, J ;
EPSTEIN, AJ .
APPLIED PHYSICS LETTERS, 1994, 65 (18) :2278-2280
[8]   Electromagnetic interference shielding efficiency of polyaniline mixtures and multilayer films [J].
Lee, CY ;
Song, HG ;
Jang, KS ;
Oh, EJ ;
Epstein, AJ ;
Joo, J .
SYNTHETIC METALS, 1999, 102 (1-3) :1346-1349
[9]   SERIES FOR COMPUTING CURRENT FLOW IN A RECTANGULAR BLOCK [J].
LOGAN, BF ;
RICE, SO ;
WICK, RF .
JOURNAL OF APPLIED PHYSICS, 1971, 42 (07) :2975-&
[10]   METHOD FOR MEASURING ELECTRICAL RESISTIVITY OF ANISOTROPIC MATERIALS [J].
MONTGOMERY, HC .
JOURNAL OF APPLIED PHYSICS, 1971, 42 (07) :2971-+