One-Pot Multiple Metal-Organic Framework Formation: Concomitant Generation of Structural Isomers or of Drastically Distinct Materials

被引：9

作者：

Cheansirisomboon, Achareeya ^{[1
,2
,3
]}

Salinas-Uber, Jorge ^{[1
]}

Massera, Chiara ^{[4
]}

Roubeau, Olivier ^{[5
,6
]}

Youngme, Sujittra ^{[2
,3
]}

Gamez, Patrick ^{[1
,7
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[2] Khon Kaen Univ, Fac Sci, Mat Chem Res Ctr, Dept Chem, Khon Kaen 40002, Thailand

[3] Khon Kaen Univ, Fac Sci, Ctr Excellence Innovat Chem, Khon Kaen 40002, Thailand

[4] Univ Parma, Dipartimento Chim, I-43124 Parma, Italy

[5] CSIC, ICMA, E-50009 Zaragoza, Spain

[6] Univ Zaragoza, E-50009 Zaragoza, Spain

[7] ICREA, Barcelona 08010, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 26期

关键词：

Metal-organic frameworks; Crystal engineering; Topological diversity; Structural isomers; Structure elucidation; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; SUPRAMOLECULAR ISOMERISM; SOLVOTHERMAL SYNTHESIS; ADSORPTION PROPERTIES; ACID; TEREPHTHALATE; TEMPERATURE; NETWORKS; SOLVENT;

D O I：

10.1002/ejic.201402475

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal reaction of 2,5-dihydroxyterephthalic acid (H(2)dhtp) and magnesium(II) nitrate in N,N-dimethylformamide (DMF) led to the simultaneous formation of two structural isomers, namely, the lvt network Mg(dhtp)(dmf)(2) (1) and the compound Mg-3(dhtp)(3)(dmf)(6)center dot 0.75H(2)O (2) with the pcu a-Po primitive cubic topology. The same reaction conditions with manganese(II) nitrate and terephthalic acid (H(2)tp) resulted in the concomitant generation of two drastically different metal-organic frameworks (MOFs), namely, Mn-2(tp)(2)-(dmf)(2) (3) and [Mn(HCOO)(3)][NC2H8] (4), in which the formato ligands and N, N-dimethylammonium cations arise from DMF degradation.

引用

页码：4385 / 4393

页数：9

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