Visible light induced H2 evolution on the hetero-junction Pt/CuCo2O4 prepared by hydrothermal route

被引:27
作者
Bagtache, R. [1 ]
Sebai, I. [2 ]
Trari, M. [3 ]
机构
[1] USTHB, Fac Chem, Lab Electrochem Corros Met & Inorgan Chem, BP 32, Algiers 16111, Algeria
[2] USTHB, Fac Chem, Lab Chem Nat Gas, BP 32, Algiers 16111, Algeria
[3] USTHB, Fac Chem, Lab Storage & Valorizat Renewable Energies, BP 32, Algiers 16111, Algeria
关键词
Hetero-system Pt/CuCo2O4; Semiconductor; Photo electrochemistry; Hydrogen; Visible light; ORDERED MESOPOROUS CUCO2O4; HIGH-PERFORMANCE; ELECTRODES; DEGRADATION; NANOWIRES;
D O I
10.1016/j.solener.2020.10.046
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The photo-electrochemistry of the hetero-junction Pt/CuCo2O4 synthesized by hydrothermal route was studied to assess its ability for the H-2 formation under visible light illumination. The X-ray diffraction is characteristic of mixed phases with narrow lines of the spinel CuCo2O4 and Pt. The sensitizer CuCo2O4 has a forbidden band (Eg) of 1.30 eV, well suited to the sun spectrum and displays p-type behavior. Its conduction band (-0.660 V-SCE), deduced from the capacitance - potential (C-2 - E) plot, is more cathodic than the H2O/H-2 level (-0.6 V-SCE), thus producing spontaneous H-2 evolution under irradiation. The photoelectrons are transferred to Pt clusters, to trigger the water reduction owing to the small H-2-over-potential. A quantum conversion yield of 0.65% is obtained under visible light (total flux: 15 mW cm(-2), 3.42 x 10(18) photons s(-1)) with H-2 evolution rate of similar to 103 mu mol g(-1) min(-1), higher than that obtained over CuCo2O4 (73 mu mol g(-1) min(-1)).
引用
收藏
页码:971 / 976
页数:6
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