Surface tearing and wall slip phenomena in extrusion of highly filled HDPE/wood flour composites

被引:91
作者
Hristov, Velichko [1 ]
Takacs, Elizabeth [1 ]
Vlachopoulos, John [1 ]
机构
[1] McMaster Univ, Dept Chem Engn, Hamilton, ON L8S 4L7, Canada
关键词
D O I
10.1002/pen.20592
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The extrudate surface tearing of highly filled high-density polyethylene (HDPE)/wood flour composites has been investigated in relation to the rheological properties and the wall slip phenomenon in capillary dies. Rotational and capillary rheometers were employed to measure the rheological properties. Mooney analysis was used for determination of wall slip velocity. The results showed considerable increase of storage modulus, dynamic and shear viscosity with increasing wood flour loading. It was also found that all wood filled composites did not obey the Cox-Merz rule. The wall slip velocity depends on wood filler content and shear rate. Generally, with increasing shear rate the slip velocity sharply increases leading to plug-like flow. It was observed that the surface of the extrudates becomes smoother with increase in shear rate and wood flour content.
引用
收藏
页码:1204 / 1214
页数:11
相关论文
共 52 条
[1]  
Archer L. A., 2005, POLYM PROCESSING INS
[2]   THE ENGINEERING REALITY OF THE YIELD STRESS [J].
ASTARITA, G .
JOURNAL OF RHEOLOGY, 1990, 34 (02) :275-277
[3]   CHARACTERIZATION OF THE SHARKSKIN DEFECT AND ITS DEVELOPMENT WITH THE FLOW CONDITIONS [J].
BEAUFILS, P ;
VERGNES, B ;
AGASSANT, JF .
INTERNATIONAL POLYMER PROCESSING, 1989, 4 (02) :78-84
[4]   THE RHEOLOGY, FIBER ORIENTATION, AND PROCESSING BEHAVIOR OF FIBER-FILLED FLUIDS [J].
BECRAFT, ML ;
METZNER, AB .
JOURNAL OF RHEOLOGY, 1992, 36 (01) :143-174
[5]   Composites reinforced with cellulose based fibres [J].
Bledzki, AK ;
Gassan, J .
PROGRESS IN POLYMER SCIENCE, 1999, 24 (02) :221-274
[6]   Thermoplastics reinforced with wood fillers: A literature review [J].
Bledzki, AK ;
Reihmane, S ;
Gassan, J .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1998, 37 (04) :451-468
[7]  
BOTROS M, 2003, INT C NEW ORL DEC 3
[8]  
CHARLTON Z, 2000, P SPE ANN TECHN C AN
[9]   APPARENT SLIP-FLOW OF POLYMER-SOLUTIONS [J].
COHEN, Y ;
METZNER, AB .
JOURNAL OF RHEOLOGY, 1985, 29 (01) :67-102
[10]   CORRELATION OF DYNAMIC AND STEADY FLOW VISCOSITIES [J].
COX, WP ;
MERZ, EH .
JOURNAL OF POLYMER SCIENCE, 1958, 28 (118) :619-622