Rhodium Catalyzed ortho-Cyanation of Arylphosphates with N-cyano-N-phenyl-p-toluenesulfonamide

被引：52
作者：
Gu, Li-Jun [1 ,2 ]
Jin, Cheng [3 ]
Wang, Rui [1 ,2 ]
Ding, Hong-Yan [1 ,2 ]
机构：
[1] Yunnan Univ Nationalities, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Yunnan, Peoples R China
[2] Yunnan Univ Nationalities, Minist Educ, Kunming 650500, Yunnan, Peoples R China
[3] New United Grp Co Ltd, Changzhou 213166, Jiangsu, Peoples R China
来源：
CHEMCATCHEM | 2014年 / 6卷 / 05期
关键词：
arylphosphonate; C-H activation; directing groups; rhodium; synthetic methods; MICROWAVE-ASSISTED SYNTHESIS; ARYL HYDROGEN PHOSPHATES; DIRECT TRANSFORMATION; ORTHO-OLEFINATION; ORTHO-ARYLATION; PRIMARY AMIDES; PRIMARY AZIDES; EFFICIENT; NITRILES; IODIDE;
D O I：
10.1002/cctc.201301076
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A rhodium-catalyzed cyanation of chelation assisted CH bonds is described. This process provided a useful method for the preparation of diverse 2-cyanated arylphosphonate and related compounds in good yields. The reaction tolerates a variety of synthetically important functional groups.
引用
收藏
页码：1225 / 1228
页数：4
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