Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal-Organic Framework

被引：10

作者：

Rohlicek, Jan ^{[1
]}

Buzek, Daniel ^{[2
]}

Brazda, Petr ^{[1
]}

Kobera, Libor ^{[3
]}

Hynek, Jan ^{[2
]}

Brus, Jiri ^{[3
]}

Lang, Kamil ^{[2
]}

Demel, Jan ^{[2
]}

机构：

[1] Czech Acad Sci, Inst Phys, Prague 18221, Czech Republic

[2] Czech Acad Sci, Inst Inorgan Chem, Husinec Rez 1001, Rez 25068, Czech Republic

[3] Czech Acad Sci, Inst Macromol Chem, Heyrovskeho Nam 2, Prague 16206 6, Czech Republic

来源：

CRYSTALS | 2019年 / 9卷 / 06期

关键词：

coordination polymer; Cerium; defects; amorphous; porosity; electron diffraction tomography; solid state NMR; MAGNETIC-PROPERTIES; CRYSTAL; HYBRIDS; SYSTEM; UIO-66;

D O I：

10.3390/cryst9060303

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Re), with the formula Ce-2(C8H10P2O4)(3), containing ditopic phenylene-1,4-bis(methylphosphinic acid) linker, was synthetized under solvothermal conditions. The crystal structure, solved using electron diffraction tomography (EDT), revealed 2D layers of octahedrally coordinated cerium atoms attached together through O-P-O bridges. The structure is nonporous, however, the modification of synthetic conditions led to unconventional metal-organic framework (or defective amorphous phase) with a specific surface area up to approximately 400 m(2) g(-1).

引用

页数：11

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