Synthesis of polymer-bound Sensitizers and their applications in the preparation of previtamin D3 from tachysterol

被引：0
|
作者：
You, CJ [1 ]
Xie, R
Gao, YY
Han, YB
Yang, GQ
Li, Y
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Photochem, Beijing 100080, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2004年 / 22卷 / 05期
关键词：
polymer-bound photosensitizer; tachysterol; vitamin D-3; photoisomerization;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two kinds of polymer-bound photosensitizers were synthesized, in which anthracene acts as sensitizer moiety, polystyrene (PS) and poly(methyl methylacrylate) (PMMA) serve as solid phase supports, respectively. The photoisomerization of tachysterol to previtamin D-3 was carried out with these polymer-bound photosensitizers in ethanol and toluene solutions. The experiment results demonstrate that these solid phase photosensitizers are efficient for the photoisomerization with good recycle property and can be simply separated from the reaction mixtures by filtration.
引用
收藏
页码：473 / 476
页数：4
相关论文
共 50 条
  • [21] Synthesis of 1-nonene from decanoic acid by polymer-bound palladium complexes
    Tanaka, S
    Shimizu, K
    Yamamoto, I
    CHEMISTRY LETTERS, 1997, (12) : 1277 - 1278
  • [22] Solid-phase synthesis of pyrazolopyridines from polymer-bound alkyne and azomethine imines
    Harju, K
    Kylanlathi, I
    Paananen, T
    Polamo, M
    Nielsen, J
    Yli-Kauhaluoma, J
    JOURNAL OF COMBINATORIAL CHEMISTRY, 2006, 8 (03): : 344 - 349
  • [23] A-Ring-Modified 2-Hydroxyethylidene Previtamin D3 Analogues: Synthesis and Biological Evaluation
    Hernandez-Martin, Alba
    Fernandez, Susana
    Verstuyf, Annemieke
    Verlinden, Lieve
    Ferrero, Miguel
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (03) : 504 - 513
  • [24] Solid-phase synthesis of substituted pyrazolones from polymer-bound β-keto esters
    Tietze, LF
    Evers, H
    Hippe, T
    Steinmetz, A
    Töpken, E
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 2001 (09) : 1631 - 1634
  • [25] POLYMER-BOUND CARBONIC-CARBOXYLIC ANHYDRIDE FUNCTIONS - PREPARATION, SITE-SITE INTERACTIONS, AND SYNTHETIC APPLICATIONS
    MARTIN, GE
    SHAMBHU, MB
    SHAKHSHIR, SR
    DIGENIS, GA
    JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (24): : 4571 - 4574
  • [26] Synthesis of 2β-substituted-14-epi-previtamin D3 and testing of its genomic activity
    Sawada, Daisuke
    Tsukuda, Yuya
    Saito, Hiroshi
    Takagi, Ken-ichiro
    Ochiai, Eiji
    Ishizuka, Seiichi
    Takenouchi, Kazuya
    Kittaka, Atsushi
    JOURNAL OF STEROID BIOCHEMISTRY AND MOLECULAR BIOLOGY, 2010, 121 (1-2): : 20 - 24
  • [27] Increase in serum 25-hydroxyvitamin-D3 in humans after sunbed exposures compared to previtamin D3 synthesis in vitro
    Orlova, Tetiana
    Moan, Johan
    Lagunova, Zoya
    Aksnes, Lage
    Terenetskaya, Irina
    Juzeniene, Asta
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2013, 122 : 32 - 36
  • [28] Selective capture of 1α,25(OH)2-previtamin D3 utilizing polymer-supported trialkylsilyl triflate in the synthesis of 1α,25-(OH)2-vitamin D3
    Doi, T
    Yoshida, M
    Hijikuro, I
    Takahashi, T
    TETRAHEDRON LETTERS, 2004, 45 (29) : 5727 - 5729
  • [29] Synthesis of two 6-s-cis locked stereoisomeric analogues of the steroid hormone 1α,25-dihydroxyvitamin D3:: 1α,25-dihydroxy-19-nor-previtamin D3 and 1β,25-dihydroxy-19-nor-previtamin D3
    Díaz, M
    Ferrero, M
    Fernández, S
    Gotor, V
    TETRAHEDRON LETTERS, 2000, 41 (05) : 775 - 779
  • [30] PREPARATION OF A NEW POLYMER-BOUND 1, 3-DIOL AND ITS APPLICATION AS A MONOBLOCKING AGENT FOR DIALDEHYDE
    REN, QS
    HUANG, WQ
    HE, BL
    ACTA CHIMICA SINICA, 1989, 47 (08) : 827 - 829
12345