Kinetics of oxidation of cycloheptanol by Os(VIII) continuously regenerated by hexacyanoferrate(III) ions

被引：0

作者：

Sati, MK ^{[1
]}

Singh, P ^{[1
]}

Tewary, G ^{[1
]}

Mehta, SPS ^{[1
]}

机构：

[1] KUMAON UNIV,DEPT CHEM,NAINI TAL 263002,INDIA

来源：

ASIAN JOURNAL OF CHEMISTRY | 1997年 / 9卷 / 04期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of cycloheptanol by Os(VIII) continuously regenerated by hexaecyanofarrate (III) ions was studied in the 0.01 M-0.1 M [OH-] range. The rate law derived on the basis of the mechanism suggested was: - d[Os(VIII)]/dt = 2kK(2)K(4)[cycloheptanol][OH-][Os(VIII)]total/1 + K2K4[cycloheptanol][OH-].

引用

页码：658 / 662

页数：5

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