Character of the thermal motion of water molecules according to the data on quasielastic incoherent scattering of slow neutrons

被引:15
作者
Bulavin, L. A. [1 ]
Malomuzh, N. P.
Pankratov, K. N.
机构
[1] Shevchenko State Univ, Kiev, Ukraine
[2] Mechnikov State Univ, Odessa, Ukraine
关键词
thermal molecule motion in water; incoherent neutron scattering; collective self-diffusion;
D O I
10.1007/s10947-006-0264-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The paper discusses the applicability of quasi-crystalline approximation to describing the thermal motion of water molecules in their normal and supercooled states. The problem is subjected to the critical analysis of experimental data on incoherent scattering of slow neutrons based on theories developed by Singwi-Sjolander [1] and Oskotsky [2] modified to duly take into account the limited applicability range of diffusion approximation. The applicability conditions of quasi-crystalline approximation are shown to be consistently satisfied only when water is in supercooled state and within a narrow temperature range above the melting temperature.
引用
收藏
页码:48 / 55
页数:8
相关论文
共 22 条
[1]  
Antonchenko V. Ya., 1991, FUNDAMENTALS WATER P
[2]   LONGITUDINAL COLLECTIVE MODES IN LIQUID WATER [J].
BALUCANI, U ;
RUOCCO, G ;
SAMPOLI, M ;
TORCINI, A ;
VALLAURI, R .
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1994, 16 (07) :817-824
[3]  
BLAZHNOV IV, 2005, IN PRESS J CHEM PHYS
[4]  
Bulavin L. A., 1986, Ukrayins'kyi Fizychnyi Zhurnal, V31, P1703
[5]  
BULAVIN LA, 2004, DOPOVIDI NAS UKRAINE, P75
[6]  
BULAVIN LA, 2004, UKR PHYS J, V49, P556
[7]  
BULAVIN LA, 1987, ZH FIZ KHIM, V61, P3270
[8]  
Chen S.-H., 1991, QUASIELASTIC INELAST, P289
[9]  
Eisenberg D., 1975, WATER STRUCTURE PROP
[10]  
FISHER IZ, 1971, ZH EKSP TEOR FIZ, V71, P1648