Storing and releasing hydrogen with a redox switch

被引:19
作者
Brayshaw, Simon K.
Green, Jennifer C.
Hazari, Nilay
McIndoe, J. Scott
Marken, Frank
Raithby, Paul R.
Weller, Andrew S. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
[3] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
基金
英国工程与自然科学研究理事会;
关键词
cluster compounds; density functional calculations; electrochemistry; hydrogen storage;
D O I
10.1002/anie.200601434
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Give and take: A molecular cluster that readily takes up and stores two molecules of H2 also rapidly releases (milliseconds) the stored H2 by a simple redox process. This process represents a new method of hydrogen storage and release from a well-defined molecular material. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6005 / 6008
页数:4
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