Directed Growth of Electroactive Metal-Organic Framework Thin Films Using Electrophoretic Deposition

被引:274
作者
Hod, Idan [1 ]
Bury, Wojciech [1 ,2 ]
Karlin, David M. [1 ]
Deria, Pravas [1 ]
Kung, Chung-Wei [1 ]
Katz, Michael J. [1 ]
So, Monica [1 ]
Klahr, Benjamin [1 ]
Jin, Danni [3 ]
Chung, Yip-Wah [3 ]
Odom, Teri W.
Farha, Omar K. [4 ]
Hupp, Joseph T.
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland
[3] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
[4] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
关键词
metal organic frameworks; electrophoretic deposition; thin films; electrochemical; FABRICATION; NUCLEATION; ALUMINA; UIO-66;
D O I
10.1002/adma.201401940
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrophoretic deposition (EPD) is used to assemble metal-organic framework (MOF) materials in nano-and micro-particulate, thin-film form. The flexibility of the method is demonstrated by the successful deposition of 4 types of MOFs: NU-1000, UiO-66, HKUST-1, and Al-MIL-53. Additionally, EPD is used to pattern the growth of NU-1000 thin films that exhibit full electrochemical activity.
引用
收藏
页码:6295 / 6300
页数:6
相关论文
共 54 条
[1]   A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions [J].
Allendorf, Mark D. ;
Schwartzberg, Adam ;
Stavila, Vitalie ;
Talin, A. Alec .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (41) :11372-11388
[2]   Patterned Growth of Metal-Organic Framework Coatings by Electrochemical Synthesis [J].
Ameloot, Rob ;
Stappers, Linda ;
Fransaer, Jan ;
Alaerts, Luc ;
Sels, Bert F. ;
De Vos, Dirk E. .
CHEMISTRY OF MATERIALS, 2009, 21 (13) :2580-2582
[3]  
Bailey RC, 2000, ADV MATER, V12, P1930, DOI 10.1002/1521-4095(200012)12:24<1930::AID-ADMA1930>3.0.CO
[4]  
2-F
[5]   Metal-Organic Framework Thin Films: From Fundamentals to Applications [J].
Betard, Angelique ;
Fischer, Roland A. .
CHEMICAL REVIEWS, 2012, 112 (02) :1055-1083
[6]   Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].
Biemmi, Enrica ;
Scherb, Camilla ;
Bein, Thomas .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+
[7]   A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].
Cavka, Jasmina Hafizovic ;
Jakobsen, Soren ;
Olsbye, Unni ;
Guillou, Nathalie ;
Lamberti, Carlo ;
Bordiga, Silvia ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851
[8]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[9]   Effect of acids and bases on electrophoretic deposition of alumina and zirconia particles in 2-propanol [J].
Cihlar, Jaroslav ;
Drdlik, Daniel ;
Cihlarova, Zora ;
Hadraba, Hynek .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2013, 33 (10) :1885-1892
[10]   Zr- and Hf-based nanoscale metal-organic frameworks as contrast agents for computed tomography [J].
deKrafft, Kathryn E. ;
Boyle, William S. ;
Burk, Laurel M. ;
Zhou, Otto Z. ;
Lin, Wenbin .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (35) :18139-18144