A study on ac and dc conductivity characteristics of Y-doped BaCeO3 modified by Ar+ ion beam

被引：9

作者：

Kim, Jae-Hwan ^{[1
]}

Tsuchiya, Bun ^{[2
]}

Nagata, Shinji ^{[2
]}

Shikama, Tatsuo ^{[2
]}

机构：

[1] Tohoku Univ, Dept Quantum Sci & Energy Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan

[2] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

来源：

SOLID STATE IONICS | 2009年 / 180卷 / 2-3期

关键词：

Ion beam; Surface modification; ERDA; AC and DC conductivity; HIGH-TEMPERATURE; OXYGEN DIFFUSION; BARIUM CERATE; PROTON; HYDROGEN; SRCEO3; OXIDES; GAS; ELECTROLYTES; ABSORPTION;

D O I：

10.1016/j.ssi.2008.12.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effects of surface modification on electrical characteristics in bulk, grain boundary and interface (electrolyte/electrode) of BaCe0.9Y0.1O3-delta were investigated, The Surface modification was performed by means of two processes: specimen was firstly irradiated by 10 keV Ar+ ion with dose of 1 x 10(18) ions/cm(2) and then exposed to air. The modified surface was investigated by elastic recoil detection analysis (ERDA) for quantitative analysis of hydrogen concentration on the surface and alternating current (AC) and direct current (DC) conductivity measurements, respectively, The ERDA results showed that hydrogen concentration and reaction rate on the modified surface increased. The increase of hydrogen concentration was explained in terms of the increase of proton due to interaction between oxygen vacancy formed by modification and H2O. In AC and DC electrical conductivity measurements, it concluded that the proton and electronic carrier generated on the surface by modification attributed to the increase of bulk, grain boundary and interface conductivity. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：271 / 275

页数：5

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