In-situ Mo nanoparticles strengthened CoCrNi medium entropy alloy

被引:45
作者
Wang, Jianying [1 ]
Yang, Hailin [1 ]
Huang, Hua [1 ]
Ruan, Jianming [1 ]
Ji, Shouxun [2 ]
机构
[1] Cent South Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[2] Brunel Univ London, Inst Mat & Mfg, Uxbridge UB8 3PH, Middx, England
基金
英国工程与自然科学研究理事会; 中国国家自然科学基金;
关键词
CoCrNi MEAs; Composites; Coating method; Spark plasma sintering; Microstructure; Mechanical properties; THERMAL-EXPANSION; MICROSTRUCTURE; DEFORMATION; BEHAVIOR; STRESS; POWDER; NANOCOMPOSITE; COMPOSITES;
D O I
10.1016/j.jallcom.2019.05.208
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In present work, the CoCrNi/Mo mixed powder was designed and fabricated by a novel coating method followed by the calcination and reduction processes. The results indicated that in-situ Mo particles distributed homogeneous among the CoCrNi gas atomized powder and no other drawbacks generated such as contamination and oxidation, the reduced Mo particles were nanoscale, and maximum size did not exceed similar to 600 nm. The SPSed CoCrNi/Mo composite with significant amount of in-situ mu phases showed improved mechanical properties: the yield strength and hardness from 352 MPa to 159 HV to 815 MPa and 375 HV, compared with the pure CoCrNi MEA (medium entropy alloy). The improved properties are mainly attributed to synergistic effects of various strengthening mechanisms, including solid solution strengthening, load transfer effect, Orowan strengthening, grain refinement, especially thermal mismatch mechanism. In addition, this could give insights on the applications of other MEA or HEA-based composites fabricated by coating method. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:576 / 586
页数:11
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