Analysis of the distribution of Tm3+ ions in LaF3 containing transparent glass-ceramics through X-ray absorption spectroscopy

被引：23

作者：

de Pablos-Martin, A. ^{[1
,3
]}

Garcia, M. A. ^{[1
]}

Munoz-Noval, A. ^{[2
]}

Castro, G. R. ^{[2
]}

Pascual, M. J. ^{[1
]}

Duran, A. ^{[1
]}

机构：

[1] CSIC, Inst Ceram & Vidrio, Madrid 28049, Spain

[2] Spanish CRG Beamline ESRF, Inst Ciencia Mat Madrid SpLine, F-38043 Grenoble 09, France

[3] Fraunhofer Inst Mech Mat IWM, D-06120 Halle, Germany

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2014年 / 384卷

关键词：

X-ray absorption spectroscopy; Oxyfluoride glass-ceramics; Fluoride crystals; Rare earths; COORDINATION ENVIRONMENTS; FLUORIDE; NANOCRYSTALS; YB3+; NMR; XAS;

D O I：

10.1016/j.jnoncrysol.2013.07.021

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Incorporation of rare-earth (RE) ions in the fluoride crystals of oxyfluoride glass-ceramics greatly improves the optical properties of these materials, such as the up-conversion emission. In this work, we present a study of this incorporation using X-ray absorption near-edge structure (XANES) spectroscopy and extended X-ray absorption fine structure (EXAFS) spectroscopy. Both techniques allow quantifying the distribution of these ions in the glass matrix and the fluoride crystals. We found that 27% of Tm3+ ions are incorporated in LaF3 nano-crystals. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：83 / 87

页数：5

共 30 条

[1] A RULE FOR CHEMICAL SHIFTS OF X-RAY ABSORPTION EDGES [J].

AGARWAL, BK ;

VERMA, LP .

JOURNAL OF PHYSICS PART C SOLID STATE PHYSICS, 1970, 3 (03) :535-&

[2]

[Anonymous], PHYS PART NUCL

[3] X-RAY ABSORPTION NEAR EDGE STRUCTURES OF INTERMEDIATE VALENCE TMSE SINGLE-CRYSTALS [J].

BIANCONI, A ;

MODESTI, S ;

CAMPAGNA, M ;

FISCHER, K ;

STIZZA, S .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1981, 14 (31) :4737-4743

[4] Structural properties and luminescence of rare-earth ions in transition-metal fluoride glasses [J].

Boulard, B ;

Guy, S ;

Vasiliev, I ;

Jestin, Y ;

Duverger, C ;

Ferrari, M .

PHILOSOPHICAL MAGAZINE, 2004, 84 (13-16) :1645-1650

[5] Europium structural environment in a sodium disilicate glass by XAS [J].

Cicconi, Maria Rita ;

Giuli, Gabriele ;

Paris, Eleonora ;

Dingwell, Donald B. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2010, 356 (35-36) :1749-1753

[6] Effects of Tm3+ Additions on the Crystallization of LaF3 Nanocrystals in Oxyfluoride Glasses: Optical Characterization and Up-Conversion [J].

de Pablos-Martin, A. ;

Ristic, D. ;

Bhattacharyya, S. ;

Hoeche, Th. ;

Mather, G. C. ;

Ramirez, M. O. ;

Soria, S. ;

Ferrari, M. ;

Righini, G. C. ;

Bausa, L. E. ;

Duran, A. ;

Pascual, M. J. .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (02) :447-457

[7] Design of oxy-fluoride glass-ceramics containing NaLaF4 nano-crystals [J].

de Pablos-Martín, A. ;

Mather, G. C. ;

Munoz, F. ;

Bhattacharyya, S. ;

Hoeche, Th ;

Jinschek, J. R. ;

Heil, T. ;

Duran, A. ;

Pascual, M. J. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2010, 356 (52-54) :3071-3079

[8] Tm3+ doped oxy-fluoride glass-ceramics containing NaLaF4 nano-crystals [J].

de Pablos-Martin, A. ;

Ramirez, M. O. ;

Duran, A. ;

Bausa, L. E. ;

Pascual, M. J. .

OPTICAL MATERIALS, 2010, 33 (02) :180-185

[9]

de Pablos-Martin A., 2012, SPIE NEWSROOM, DOI DOI 10.1117/2.1201209.004335

[10] Crystallization Kinetics of LaF3 Nanocrystals in an Oxyfluoride Glass [J].

de Pablos-Martin, Araceli ;

Hemono, Nicolas ;

Mather, Glenn C. ;

Bhattacharyya, Sommnath ;

Hoeche, Thomas ;

Bornhoeft, Hansjoerg ;

Deubener, Joachim ;

Munoz, Francisco ;

Duran, Alicia ;

Pascual, Maria J. .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (08) :2420-2428

← 1 2 3 →