Ethanol electrooxidation on Pt/C catalysts promoted with praseodymium oxide nanorods

被引：19

作者：

Wang, Yi ^{[1
]}

Nguyen, Truong Son ^{[1
]}

Wang, Cheng ^{[2
]}

Wang, Xin ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 639798, Singapore

[2] Chinese Acad Sci, State Key Lab Rare Earth Resources Utilizat, Changchun Inst Appl Chem, Beijing 100864, Peoples R China

来源：

DALTON TRANSACTIONS | 2009年 / 37期

关键词：

ELECTROCHEMICAL OXIDATION; METHANOL; ELECTROCATALYSTS; PLATINUM;

D O I：

10.1039/b909324a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Pt/C electrocatalysts containing Pr6O11 nanorods were successfully prepared. By various electrochemical characterization methods, it was demonstrated that the Pr6O11 nanorods have an obviously promotive role for ethanol electrooxidation catalyzed by Pt/C. However, according to the stripping experiment, the promotive effect of Pr6O11 does not result from the easier electrooxidation of the intermediate adsorbate on Pt-Pr6O11/C than on Pt/C. It was supposed that Pr6O11 could promote a certain step in ethanol oxidation, and that the special morphology of the nanorods could further enhance the activity compared with nanoparticles.

引用

页码：7606 / 7609

页数：4

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