Low-temperature Hydrogenation of Toluene by Electrolysis of Water with Hydrogen Permeable Palladium Membrane Electrode

被引：6
|
作者：
Sato, Takafumi [1 ]
Takada, Ayaka [1 ]
Itoh, Naotsugu [1 ]
机构：
[1] Utsunomiya Univ, Dept Mat & Environm Chem, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 04期
关键词：
Electrolysis of water; Hydrogenation of toluene; Palladium membrane electrode; SHEET ELECTRODE; PD SHEET; CATHODE; PERMEATION; REACTOR; STYRENE; ALLOY;
D O I：
10.1246/cl.161164
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogenation of toluene proceeded with hydrogen derived from the electrolysis of water with an electrical cell that a hydrogen permeable palladium membrane was the cathode. The hydrogenation occurred with selectively permeated hydrogen through the membrane in a catalytic layer at more than 313K and the rate of hydrogenation increased with increasing temperature. This system was stable at least several hours and about a half of hydrogen produced by the electrolysis can be used for hydrogenation.
引用
收藏
页码：477 / 480
页数：4
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