Low-temperature Hydrogenation of Toluene by Electrolysis of Water with Hydrogen Permeable Palladium Membrane Electrode

被引：6
|
作者：
Sato, Takafumi [1 ]
Takada, Ayaka [1 ]
Itoh, Naotsugu [1 ]
机构：
[1] Utsunomiya Univ, Dept Mat & Environm Chem, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 04期
关键词：
Electrolysis of water; Hydrogenation of toluene; Palladium membrane electrode; SHEET ELECTRODE; PD SHEET; CATHODE; PERMEATION; REACTOR; STYRENE; ALLOY;
D O I：
10.1246/cl.161164
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogenation of toluene proceeded with hydrogen derived from the electrolysis of water with an electrical cell that a hydrogen permeable palladium membrane was the cathode. The hydrogenation occurred with selectively permeated hydrogen through the membrane in a catalytic layer at more than 313K and the rate of hydrogenation increased with increasing temperature. This system was stable at least several hours and about a half of hydrogen produced by the electrolysis can be used for hydrogenation.
引用
收藏
页码：477 / 480
页数：4
相关论文
共 50 条
  • [1] Using a hydrogen-permeable palladium membrane electrode to produce hydrogen from water and hydrogenate toluene
    Sato, Takafumi
    Sato, Shuhei
    Itoh, Naotsugu
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (12) : 5419 - 5427
  • [2] Membrane Electrolysis of Toluene Hydrogenation with Water Decomposition for Energy Carrier Synthesis
    Mitsushima, Shigenori
    Takakuwa, Yasutomo
    Nagasawa, Kensaku
    Sawaguchi, Yuki
    Kohno, Yuji
    Matsuzawa, Koichi
    Awaludin, Zaenal
    Kato, Akihiro
    Nishiki, Yoshinori
    ELECTROCATALYSIS, 2016, 7 (02) : 127 - 131
  • [3] Membrane Electrolysis of Toluene Hydrogenation with Water Decomposition for Energy Carrier Synthesis
    Shigenori Mitsushima
    Yasutomo Takakuwa
    Kensaku Nagasawa
    Yuki Sawaguchi
    Yuji Kohno
    Koichi Matsuzawa
    Zaenal Awaludin
    Akihiro Kato
    Yoshinori Nishiki
    Electrocatalysis, 2016, 7 : 127 - 131
  • [4] Spectroscopic study of low-temperature hydrogen absorption in palladium
    Ienaga, K.
    Takata, H.
    Onishi, Y.
    Inagaki, Y.
    Tsujii, H.
    Kimura, T.
    Kawae, T.
    APPLIED PHYSICS LETTERS, 2015, 106 (02)
  • [5] Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale
    Ayers, Katherine
    Danilovic, Nemanja
    Ouimet, Ryan
    Carmo, Marcelo
    Pivovar, Bryan
    Bornstein, Marius
    ANNUAL REVIEW OF CHEMICAL AND BIOMOLECULAR ENGINEERING, VOL 10, 2019, 10 : 219 - 239
  • [6] High entropy materials as emerging electrocatalysts for hydrogen production through low-temperature water electrolysis
    Esquius, Jonathan Ruiz
    Liu, Lifeng
    MATERIALS FUTURES, 2023, 2 (02):
  • [7] PALLADIUM ALLOYS AS HYDROGEN PERMEABLE CATALYSTS IN HYDROGENATION AND DEHYDROGENATION REACTIONS
    GRYAZNOV, VM
    ERMILOVA, MM
    MOROZOVA, LS
    OREKHOVA, NV
    POLYAKOVA, VP
    ROSHAN, NR
    SAVITSKY, EM
    PARFENOVA, NI
    JOURNAL OF THE LESS-COMMON METALS, 1983, 89 (02): : 529 - 535
  • [8] On the Change in Properties of Water Subjected to Low-Temperature Plasma Electrolysis
    A. V. Kravchenko
    S. A. Berlizova
    A. F. Nesterenko
    V. S. Kublanovskii
    High Energy Chemistry, 2004, 38 : 333 - 337
  • [9] Low-temperature water electrolysis: fundamentals, progress, and new strategies
    Li, Wei
    Tian, Hanchen
    Ma, Liang
    Wang, Yi
    Liu, Xingbo
    Gao, Xuefei
    MATERIALS ADVANCES, 2022, 3 (14): : 5598 - 5644
  • [10] On the change in properties of water subjected to low-temperature plasma electrolysis
    Kravchenko, AV
    Berlizova, SA
    Nesterenko, AF
    Kublanovskii, VS
    HIGH ENERGY CHEMISTRY, 2004, 38 (05) : 333 - 337
12345