Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light

被引：1180

作者：

Chen, Xiufang ^{[1
,2
]}

Zhang, Jinshui ^{[1
]}

Fu, Xianzhi ^{[1
]}

Antonietti, Markus ^{[2
]}

Wang, Xinchen ^{[1
,2
]}

机构：

[1] Fuzhou Univ, State Key Lab Breeding Base Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

[2] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 33期

关键词：

GRAPHITIC CARBON NITRIDE; CATALYST; HYDROXYLATION;

D O I：

10.1021/ja903923s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis. Here exemplified for phenol synthesis, Fe-g-C3N4/SBA-15 is able to oxidize benzene to phenol with H2O2 even without the aid of strong acids or alkaline promoters. By taking advantage of both catalysis and photocatalyisis functions of g-C3N4 nanoparticles, the yield of the phenol. can be markedly promoted.

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页码：11658 / +

页数：3

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