New Opportunities in Free Radical Photopolymerization Free Radical Promoted Cationic Polymerization Based on Silyl Radical Chemistry

被引：7

作者：

Lalevee, J. ^{[1
]}

El Roz, M. ^{[1
]}

Tehfe, M. A. ^{[1
]}

Alaaeddine, M. ^{[1
]}

Allonas, X. ^{[1
]}

Fouassier, J. -P. ^{[1
]}

机构：

[1] Univ Haute Alsace, CNRS, Dept Photochem, ENSCMu, F-68093 Mulhouse, France

来源：

JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY | 2009年 / 22卷 / 05期

关键词：

photoinitiator; laser spectroscopy; photopolymerization; VISIBLE-LIGHT; AERATED MEDIA; PHOTOINITIATORS; REACTIVITY; SYSTEMS; ABILITY;

D O I：

10.2494/photopolymer.22.587

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New compounds based on the silyl radical chemistry are presented as coinitiators for free radical photopolymerization (FRP) or sources of radicals for free radical promoted cationic photopolymerization (FRPCP). The ability of these structures in the initiation of both FRP and FRPCP processes is investigated. High rates of polymerization and high final conversions are obtained. Laser flash photolysis is used for the analysis of the silyl radical formation.

引用

页码：587 / 590

页数：4

共 50 条

[31] Novel allylic phosphonium salts in free radical accelerated cationic polymerization [J].

Mukesh Kumar Gupta ;

Raj Pal Singh .

Polymer Bulletin, 2009, 62 :271-280

[32] Radical-Promoted Visible Light Photoinitiated Cationic Polymerization of Epoxides [J].

Crivello, James V. .

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2009, 46 (05) :474-483

[33] A thioxanthone-based photocaged superbase for highly effective free radical photopolymerization [J].

He, Ming-Hui ;

Xu, Rui-Xin ;

Chen, Guang-Xue ;

Zeng, Zhao-Hua ;

Yang, Jian-Wen .

CHINESE CHEMICAL LETTERS, 2014, 25 (11) :1445-1448

[34] Remarkable Versatility of Silane/lodonium Salt as Redox Free Radical, Cationic, and Photopolymerization Initiators [J].

Wang, Dengxia ;

Szillat, Florian ;

Fouassier, Jean Pierre ;

Lalevee, Jacques .

MACROMOLECULES, 2019, 52 (15) :5638-5645

[35] Novel phenylamine-based oxime ester photoinitiators for LED-induced free radical, cationic, and hybrid polymerization [J].

Hammoud, Fatima ;

Lee, Zhong-Han ;

Graff, Bernadette ;

Hijazi, Akram ;

Lalevee, Jacques ;

Chen, Yung-Chung .

JOURNAL OF POLYMER SCIENCE, 2021, 59 (15) :1711-1723

[36] Coinitiators Based on Group 14 Elements in Photoinitiating Systems for Radical and Cationic Polymerization [J].

El-Roz, M. ;

Lalevee, J. ;

Morlet-Savary, F. ;

Allonas, X. ;

Fouassier, J. P. .

MACROMOLECULES, 2009, 42 (13) :4464-4469

[37] Sugar overcomes oxygen inhibition in photoinitiated free radical polymerization [J].

Oytun, Faruk ;

Kahveci, Muhammet U. ;

Yagci, Yusuf .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (08) :1685-1689

[38] Photoinitiated Metal Free Living Radical and Cationic Polymerizations [J].

Ciftci, Mustafa ;

Yilmaz, Gorkem ;

Yagci, Yusuf .

JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY, 2017, 30 (04) :385-392

[39] A new visible light bimolecular photoinitiator system for free radical polymerization [J].

Chen, Yu ;

Li, Guanglei ;

Han, Junru ;

Wang, Tao .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2011, 222 (2-3) :330-335

[40] Evolution of material properties during free radical photopolymerization [J].

Wu, Jiangtao ;

Zhao, Zeang ;

Hamel, Craig M. ;

Mu, Xiaoming ;

Kuang, Xiao ;

Guo, Zaoyang ;

Qi, H. Jerry .

JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2018, 112 :25-49

← 1 2 3 4 5 →