New Opportunities in Free Radical Photopolymerization Free Radical Promoted Cationic Polymerization Based on Silyl Radical Chemistry

被引：7
|
作者：
Lalevee, J. [1 ]
El Roz, M. [1 ]
Tehfe, M. A. [1 ]
Alaaeddine, M. [1 ]
Allonas, X. [1 ]
Fouassier, J. -P. [1 ]
机构：
[1] Univ Haute Alsace, CNRS, Dept Photochem, ENSCMu, F-68093 Mulhouse, France
来源：
JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY | 2009年 / 22卷 / 05期
关键词：
photoinitiator; laser spectroscopy; photopolymerization; VISIBLE-LIGHT; AERATED MEDIA; PHOTOINITIATORS; REACTIVITY; SYSTEMS; ABILITY;
D O I：
10.2494/photopolymer.22.587
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New compounds based on the silyl radical chemistry are presented as coinitiators for free radical photopolymerization (FRP) or sources of radicals for free radical promoted cationic photopolymerization (FRPCP). The ability of these structures in the initiation of both FRP and FRPCP processes is investigated. High rates of polymerization and high final conversions are obtained. Laser flash photolysis is used for the analysis of the silyl radical formation.
引用
收藏
页码：587 / 590
页数：4
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