Lithium Based Metal-Organic Framework with Exceptional Stability

被引：87
作者：
Banerjee, Debasis [1 ]
Kim, Sun Jin [2 ]
Parise, John B. [1 ,3 ]
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[2] Korea Inst Sci & Technol, Nanomat Res Ctr, Seoul 130650, South Korea
[3] SUNY Stony Brook, Dept Geosci, Stony Brook, NY 11794 USA
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 05期
基金：
美国国家科学基金会;
关键词：
HYDROGEN STORAGE; COORDINATION POLYMER; STRUCTURAL-CHARACTERIZATION; CARBON-DIOXIDE; GAS SORPTION; ADSORPTION; CAPACITY; SEPARATION; TRIAZOLE; NETWORK;
D O I：
10.1021/cg8014157
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A three-dimensional lithium based metal-organic framework Li-2(2,6-NDC) (1); UL-MOF-1, UL ultralight; NDC = napthalenedicarboxylate; space group P2(1)/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) angstrom, beta = 98.659(9)degrees, V = 471.6(4) angstrom(3) was synthesized. The framework is stable to 610 degrees C. The synthesis of 1 was achieved using solvothermal methods in N,N-dimethylformamide at 180 degrees C and was characterized by single crystal X-ray diffraction. The structure consists of layers of two-dimensional antifluorite related LiO connected by the NDC linker.
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页码：2500 / 2503
页数：4
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