Synthesis of 9,9′,12,12′-substituted cobalt bis(dicarbollide) derivatives

被引：16

作者：

Anufriev, S. A. ^{[1
]}

Sivaev, I. B. ^{[1
]}

Bregadze, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

ortho-carboranes; nido-carboranes; cobalt bis(dicarbollide); cobalt derivatives; MOLECULAR CONDUCTORS; CARBORANES; CHEMISTRY; SALTS;

D O I：

10.1007/s11172-015-0924-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A partial degradation of 9,12-disubstituted derivatives of ortho-carboranes 9,12-X-2-1,2-C2B10H10 (X = Br, Alk, Ar) led to the corresponding substituted nido-carboranes [5,6-X-2-7,8-C2B9H10](-), which on the reaction with cobalt(II) chloride gave new 9,9',12,12'-tetrasubstituted derivatives of cobalt bis(dicarbollide) [9,9',12,12'-X-4-3,3'-Co(1,2-C2B9H9)(2)](-).

引用

页码：712 / 717

页数：6

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