Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus-aluminum ligand to gold

被引：73

作者：

Devillard, Marc ^{[1
,2
]}

Nicolas, Emmanuel ^{[3
]}

Appelt, Christian ^{[4
]}

Backs, Jana ^{[4
]}

Mallet-Ladeira, Sonia ^{[5
]}

Bouhadir, Ghenwa ^{[1
,2
]}

Slootweg, J. Chris ^{[3
]}

Uhl, Werner ^{[4
]}

Bourissou, Didier ^{[1
,2
]}

机构：

[1] Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France

[2] CNRS, LHFA, UMR 5069, F-31062 Toulouse, France

[3] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands

[4] Univ Munster, Inst Anorgan & Analyt Chem Westfal, D-48149 Munster, Germany

[5] Univ Toulouse 3, Inst Chim Toulouse FR 2599, F-31062 Toulouse 9, France

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 94期

关键词：

FRUSTRATED LEWIS PAIR; CARBON-DIOXIDE; CATALYSIS; ACTIVATION; BORANE; DERIVATIVES; REACTIVITY; HYDROGEN; DIPHOSPHINE; MOLECULES;

D O I：

10.1039/c4cc06992g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination of Mes(2)PC(=CHPh)AltBu(2) to metal chlorides has been studied. Bridging P -> M-Cl -> Al coordinations were observed with Rh and Pd fragments, while chloride abstraction systematically occurred with gold. The resulting zwitterionic complexes have been fully characterized and analyzed by DFT calculations.

引用

页码：14805 / 14808

页数：4

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