A Computational Meta-Analysis of UCl3 Cyclic Voltammograms in LiCl-KCl Electrolyte

被引：16

作者：

Cumberland, Riley M. ^{[1
]}

Yim, Man-Sung ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Taejon 30701, South Korea

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2014年 / 161卷 / 04期

关键词：

SPENT NUCLEAR-FUEL; CADMIUM POOL; MOLTEN-SALT; URANIUM; ELECTROREFINER; BEHAVIOR;

D O I：

10.1149/2.033404jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

As a way to characterize the values of key parameters for modeling electrochemical transport of elements in a molten salt system, a meta-analysis of CV reduction peaks for UCl3 in LiCl-KCl eutectic was performed. Published CV data was fit using least squares fitting software coupled with electrochemical simulation software. The analysis yielded estimates of apparent standard potential, the diffusion coefficient, and the exchange current density for each reaction. The results for the UCl3 reduction peak matched well with existing data. (C) 2014 The Electrochemical Society. All rights reserved.

引用

页码：D147 / D149

页数：3

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