Cathodic reactivity of alkaline metal iodides toward platinum bulk. The formation of new reducing phases

被引：13

作者：

Cougnon, C ^{[1
]}

Simonet, J ^{[1
]}

机构：

[1] Univ Rennes 1, Lab Electrochim, UMR 6510, F-35042 Rennes, France

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2002年 / 4卷 / 03期

关键词：

platinum cathodes; chemically modified electrodes; alkaline electrolytes; iodides;

D O I：

10.1016/S1388-2481(02)00272-2

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Cathodic polarization of platinum electrodes in aprotic dipolar solvents such as carefully dried dimethylformamide containing a large palette of electrolytes affords a reduced phase whose thickness can reach several microns. The nature and the conditions for the cathodic reactivity of alkaline iodides are described as well as the information on the stability of these reduced phases, especially in the presence of acceptors. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：266 / 271

页数：6

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