A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction

被引:757
作者
Long, Xia [1 ]
Li, Jinkai [1 ]
Xiao, Shuang [1 ]
Yan, Keyou [1 ]
Wang, Zilong [1 ]
Chen, Haining [1 ]
Yang, Shihe [1 ]
机构
[1] Hong Kong Univ Sci & Technol, William Mong Inst Nano Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
关键词
electrochemical catalyst; FeNi; graphene; layered double hydroxide; oxygen evolution reaction; LAYERED DOUBLE HYDROXIDE; WATER OXIDATION; OXIDE SURFACES; FILMS; PEROVSKITES; CATALYSIS;
D O I
10.1002/anie.201402822
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cost-effective electrocatalysts for the oxygen evolution reaction (OER) are critical to energy conversion and storage processes. A novel strategy is used to synthesize a non-noble-metal-based electrocatalyst of the OER by finely combining layered FeNi double hydroxide that is catalytically active and electric conducting graphene sheets, taking advantage of the electrostatic attraction between the two positively charged nanosheets. The synergy between the catalytic activity of the double hydroxide and the enhanced electron transport arising from the graphene resulted in superior electrocatalytic properties of the FeNi-GO hybrids for the OER with over-potentials as low as 0.21 V, which was further reduced to 0.195 V after the reduction treatment. Moreover, the turnover frequency at the overpotential of 0.3 V has reached 1 s(-1), which is much higher than those previously reported for non-noble-metal-based electrocatalysts.
引用
收藏
页码:7584 / 7588
页数:5
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